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Cerium(IV) Oxide–cerium(III) Oxide Cycle
The cerium(IV) oxide–cerium(III) oxide cycle or CeO2/Ce2O3 cycle is a two-step thermochemical process that employs cerium(IV) oxide and cerium(III) oxide for hydrogen production. The cerium-based cycle allows the separation of H2 and O2 in two steps, making high-temperature gas separation redundant. Process description The thermochemical two-step water splitting process (thermochemical cycle) uses redox systems: *Dissociation: 2 CeO2 → Ce2O3 + 0.5 O2 *Hydrolysis: Ce2O3 + H2O → 2 CeO2 + H2 For the first endothermic step, cerium(IV) oxide is thermally dissociated in an inert gas atmosphere at and 100-200 mbar into cerium(III) oxide and oxygen. In the second exothermic step cerium(III) oxide reacts at – in a fixed bed reactor with water and produces hydrogen and cerium(IV) oxide. See also * Copper–chlorine cycle * Heliostat * Hybrid sulfur cycle * HYDROSOL * Iron oxide cycle * Solar thermal energy * Sulfur–iodine cycle * Zinc–zinc oxide cycle For chemical react ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ceria Cycle
Cerium(IV) oxide, also known as ceric oxide, ceric dioxide, ceria, cerium oxide or cerium dioxide, is an oxide of the rare-earth metal cerium. It is a pale yellow-white powder with the chemical formula CeO2. It is an important commercial product and an intermediate in the purification of the element from the ores. The distinctive property of this material is its reversible conversion to a Non-stoichiometric compound, non-stoichiometric oxide. Production Cerium occurs naturally as oxides, always as a mixture with other rare-earth elements. Its principal ores bastnaesite and monazite. After extraction of the metal ions into aqueous base, Ce is separated from that mixture by addition of an oxidant followed by adjustment of the pH. This step exploits the low solubility of CeO2 and the fact that other rare-earth elements resist oxidation.. Cerium(IV) oxide is formed by the calcination of cerium oxalate or cerium hydroxide. Cerium also forms cerium(III) oxide, , which is unstable ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inert Gas
An inert gas is a gas that does not readily undergo chemical reactions with other chemical substances and therefore does not readily form chemical compounds. The noble gases often do not react with many substances and were historically referred to as the inert gases. Inert gases are used generally to avoid unwanted chemical reactions degrading a sample. These undesirable chemical reactions are often oxidation and hydrolysis reactions with the oxygen and moisture in air. The term ''inert gas'' is context-dependent because several of the noble gases can be made to react under certain conditions. Purified argon gas is the most commonly used inert gas due to its high natural abundance (78.3% N2, 1% Ar in air) and low relative cost. Unlike noble gases, an inert gas is not necessarily elemental and is often a compound gas. Like the noble gases, the tendency for non-reactivity is due to the valence, the outermost electron shell, being complete in all the inert gases. This is a tendency, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Reactions
A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking of chemical bonds between atoms, with no change to the nuclei (no change to the elements present), and can often be described by a chemical equation. Nuclear chemistry is a sub-discipline of chemistry that involves the chemical reactions of unstable and radioactive elements where both electronic and nuclear changes can occur. The substance (or substances) initially involved in a chemical reaction are called reactants or reagents. Chemical reactions are usually characterized by a chemical change, and they yield one or more products, which usually have properties different from the reactants. Reactions often consist of a sequence of individual sub-steps, the so-called elementary reactions, and the information on the precise course of acti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zinc–zinc Oxide Cycle
For chemical reactions, the zinc–zinc oxide cycle or Zn–ZnO cycle is a two step thermochemical cycle based on zinc and zinc oxide for hydrogen production with a typical efficiency around 40%. Process description The thermochemical two-step water splitting process uses redox systems: *Dissociation: ZnO → Zn + 1/2 O2 *Hydrolysis: Zn + H2O → ZnO + H2 For the first endothermic step concentrating solar power is used in which zinc oxide is thermally dissociated at into zinc and oxygen. In the second non-solar exothermic step zinc reacts at with water and produces hydrogen and zinc oxide. The temperature level is realized by using a solar power tower and a set of heliostats to collect the solar thermal energy. See also * Cerium(IV) oxide–cerium(III) oxide cycle * Copper–chlorine cycle * Hydrosol-2 * Hybrid sulfur cycle * Iron oxide cycle * Sulfur–iodine cycle The sulfur–iodine cycle (S–I cycle) is a three-step thermochemical cycle used to produce hydrogen. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfur–iodine Cycle
The sulfur–iodine cycle (S–I cycle) is a three-step thermochemical cycle used to produce hydrogen. The S–I cycle consists of three chemical reactions whose net reactant is water and whose net products are hydrogen and oxygen. All other chemicals are recycled. The S–I process requires an efficient source of heat. Process description The three reactions that produce hydrogen are as follows: # I2 + SO2 + 2 H2O 2 HI + H2SO4 (); Bunsen reaction #*The HI is then separated by distillation or liquid/liquid gravitic separation. #2 H2SO4 2 SO2 + 2 H2O + O2 () #*The water, SO2 and residual H2SO4 must be separated from the oxygen byproduct by condensation. #2 HI I2 + H2 () #*Iodine and any accompanying water or SO2 are separated by condensation, and the hydrogen product remains as a gas. : : Net reaction: 2 H2O → 2 H2 + O2 The sulfur and iodine compounds are recovered and reused, hence the consideration of the process as a cycle. This S–I process is a chemical heat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solar Thermal Energy
Solar thermal energy (STE) is a form of energy and a technology for harnessing solar energy to generate thermal energy for use in industry, and in the residential and commercial sectors. Solar thermal collectors are classified by the United States Energy Information Administration as low-, medium-, or high-temperature collectors. Low-temperature collectors are generally unglazed and used to heat swimming pools or to heat ventilation air. Medium-temperature collectors are also usually flat plates but are used for heating water or air for residential and commercial use. High-temperature collectors concentrate sunlight using mirrors or lenses and are generally used for fulfilling heat requirements up to 300 deg C / 20 bar pressure in industries, and for electric power production. Two categories include Concentrated Solar Thermal (CST) for fulfilling heat requirements in industries, and Concentrated Solar Power (CSP) when the heat collected is used for electric power generation. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iron Oxide Cycle
For chemical reactions, the iron oxide cycle (Fe3O4/FeO) is the original two-step thermochemical cycle proposed for use for hydrogen production. It is based on the reduction and subsequent oxidation of iron ions, particularly the reduction and oxidation between Fe3+ and Fe2+. The ferrites, or iron oxide, begins in the form of a spinel and depending on the reaction conditions, dopant metals and support material forms either Wüstites or different spinels. Process description The thermochemical two-step water splitting process uses two redox steps. The steps of solar hydrogen production by iron based two-step cycle are: : \begin \ce &\ce \\ \ce & \ce \end Where M can by any number of metals, often Fe itself, Co, Ni, Mn, Zn or mixtures thereof. The endothermic reduction step (1) is carried out at high temperatures greater than , though the "Hercynite cycle" is capable of temperatures as low as . The oxidative water splitting step (2) occurs at a lower ~ temperature which prod ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hybrid Sulfur Cycle
The hybrid sulfur cycle (HyS) is a two-step water-splitting process intended to be used for hydrogen production. Based on sulfur oxidation and reduction, it is classified as a hybrid thermochemical cycle because it uses an electrochemical Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference, as a measurable and quantitative phenomenon, and identifiable chemical change, with the potential difference as an outco ... (instead of a thermochemical) reaction for one of the two steps. The remaining thermochemical step is shared with the sulfur-iodine cycle. The Hybrid sulphur cycle (HyS)was initially proposed and developed by Westinghouse Electric Corp. in the 1970s, so it is also known as the "Westinghouse" cycle. Current development efforts in the United States are being led by the Savannah River National Laboratory. Process description The two reactions in the HyS cycle are as follows: # H2SO4 → H2O + SO ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Heliostat
A heliostat (from ''helios'', the Greek word for ''sun'', and ''stat'', as in stationary) is a device that includes a mirror, usually a plane mirror, which turns so as to keep reflecting sunlight toward a predetermined target, compensating for the sun's apparent motions in the sky. The target may be a physical object, distant from the heliostat, or a direction in space. To do this, the reflective surface of the mirror is kept perpendicular to the bisector of the angle between the directions of the sun and the target as seen from the mirror. In almost every case, the target is stationary relative to the heliostat, so the light is reflected in a fixed direction. According to contemporary sources the heliostata, as it was called at first, was invented by Willem 's Gravesande (1688–1742). Other contenders are Giovanni Alfonso Borelli (1608–1679) and Daniel Gabriel Fahrenheit (1686–1736). A Heliostat designed by George Johnstone Storey is in the Science Museum Group collec ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Copper–chlorine Cycle
The copper–chlorine cycle (Cu–Cl cycle) is a four-step thermochemical cycle for the production of hydrogen. The Cu–Cl cycle is a hybrid process that employs both Thermochemistry, thermochemical and electrolysis steps. It has a maximum temperature requirement of about 530 degrees Celsius. The Cu–Cl cycle involves four chemical reactions for water splitting, whose net reaction decomposes water into hydrogen and oxygen. All other chemicals are recycled. The Cu–Cl process can be linked with nuclear plants or other heat sources such as solar and industrial waste heat to potentially achieve higher efficiencies, lower environmental impact and lower costs of hydrogen production than any other conventional technology. The Cu–Cl cycle is one of the prominent thermochemical cycles under development within the Generation IV reactor, Generation IV International Forum (GIF). Through GIF, over a dozen countries around the world are developing the next generation of nuclear reactor ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen
Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, and highly combustible. Hydrogen is the most abundant chemical substance in the universe, constituting roughly 75% of all normal matter.However, most of the universe's mass is not in the form of baryons or chemical elements. See dark matter and dark energy. Stars such as the Sun are mainly composed of hydrogen in the plasma state. Most of the hydrogen on Earth exists in molecular forms such as water and organic compounds. For the most common isotope of hydrogen (symbol 1H) each atom has one proton, one electron, and no neutrons. In the early universe, the formation of protons, the nuclei of hydrogen, occurred during the first second after the Big Bang. The emergence of neutral hydrogen atoms throughout the universe occurred about 370,000 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Exothermic
In thermodynamics, an exothermic process () is a thermodynamic process or reaction that releases energy from the system to its surroundings, usually in the form of heat, but also in a form of light (e.g. a spark, flame, or flash), electricity (e.g. a battery), or sound (e.g. explosion heard when burning hydrogen). The term ''exothermic'' was first coined by 19th-century French chemist Marcellin Berthelot. The opposite of an exothermic process is an endothermic process, one that absorbs energy usually in the form of heat. The concept is frequently applied in the physical sciences to chemical reactions where chemical bond energy is converted to thermal energy (heat). Two types of chemical reactions Exothermic and endothermic describe two types of chemical reactions or systems found in nature, as follows: Exothermic After an exothermic reaction, more energy has been released to the surroundings than was absorbed to initiate and maintain the reaction. An example would be the burn ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
