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CLAW Hypothesis
The CLAW hypothesis proposes a negative feedback loop that operates between ocean ecosystems and the Earth's climate. The hypothesis specifically proposes that particular phytoplankton that produce dimethyl sulfide are responsive to variations in climate forcing, and that these responses act to stabilise the temperature of the Earth's atmosphere. The CLAW hypothesis was originally proposed by Robert Jay Charlson, James Lovelock, Meinrat Andreae and Stephen G. Warren, and takes its acronym from the first letter of their surnames. CLAW hypothesis The hypothesis describes a feedback loop that begins with an increase in the available energy from the sun acting to increase the growth rates of phytoplankton by either a physiological effect (due to elevated temperature) or enhanced photosynthesis (due to increased irradiance). Certain phytoplankton, such as coccolithophorids, synthesise dimethylsulfoniopropionate (DMSP), and their enhanced growth increases the production of this ...
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Negative Feedback
Negative feedback (or balancing feedback) occurs when some function (Mathematics), function of the output of a system, process, or mechanism is feedback, fed back in a manner that tends to reduce the fluctuations in the output, whether caused by changes in the input or by other disturbances. Whereas positive feedback tends to lead to instability via exponential growth, oscillation or chaos theory, chaotic behavior, negative feedback generally promotes stability. Negative feedback tends to promote a settling to List of types of equilibrium, equilibrium, and reduces the effects of perturbations. Negative feedback loops in which just the right amount of correction is applied with optimum timing can be very stable, accurate, and responsive. Negative feedback is widely used in mechanical and electronic engineering, and also within living organisms, and can be seen in many other fields from chemistry and economics to physical systems such as the climate. General negative feedback ...
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Irradiance
In radiometry, irradiance is the radiant flux ''received'' by a ''surface'' per unit area. The SI unit of irradiance is the watt per square metre (W⋅m−2). The CGS unit erg per square centimetre per second (erg⋅cm−2⋅s−1) is often used in astronomy. Irradiance is often called intensity, but this term is avoided in radiometry where such usage leads to confusion with radiant intensity. In astrophysics, irradiance is called ''radiant flux''. Spectral irradiance is the irradiance of a surface per unit frequency or wavelength, depending on whether the spectrum is taken as a function of frequency or of wavelength. The two forms have different dimensions and units: spectral irradiance of a frequency spectrum is measured in watts per square metre per hertz (W⋅m−2⋅Hz−1), while spectral irradiance of a wavelength spectrum is measured in watts per square metre per metre (W⋅m−3), or more commonly watts per square metre per nanometre (W⋅m−2⋅nm−1). Mathematical ...
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Homeostasis
In biology, homeostasis (British English, British also homoeostasis) Help:IPA/English, (/hɒmɪə(ʊ)ˈsteɪsɪs/) is the state of steady internal, physics, physical, and chemistry, chemical conditions maintained by organism, living systems. This is the condition of optimal functioning for the organism and includes many variables, such as body temperature and fluid balance, being kept within certain pre-set limits (homeostatic range). Other variables include the pH of extracellular fluid, the concentrations of sodium, potassium and calcium ions, as well as that of the blood sugar level, and these need to be regulated despite changes in the environment, diet, or level of activity. Each of these variables is controlled by one or more regulators or homeostatic mechanisms, which together maintain life. Homeostasis is brought about by a natural resistance to change when already in the optimal conditions, and equilibrium is maintained by many regulatory mechanisms: it is thought to be ...
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Damping Ratio
Damping is an influence within or upon an oscillatory system that has the effect of reducing or preventing its oscillation. In physical systems, damping is produced by processes that dissipate the energy stored in the oscillation. Examples include viscous drag (a liquid's viscosity can hinder an oscillatory system, causing it to slow down; see viscous damping) in mechanical systems, resistance in electronic oscillators, and absorption and scattering of light in optical oscillators. Damping not based on energy loss can be important in other oscillating systems such as those that occur in biological systems and bikes (ex. Suspension (mechanics)). Not to be confused with friction, which is a dissipative force acting on a system. Friction can cause or be a factor of damping. The damping ratio is a dimensionless measure describing how oscillations in a system decay after a disturbance. Many systems exhibit oscillatory behavior when they are disturbed from their position of sta ...
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Schematic
A schematic, or schematic diagram, is a designed representation of the elements of a system using abstract, graphic symbols rather than realistic pictures. A schematic usually omits all details that are not relevant to the key information the schematic is intended to convey, and may include oversimplified elements in order to make this essential meaning easier to grasp, as well as additional organization of the information. For example, a subway map intended for passengers may represent a subway station with a dot. The dot is not intended to resemble the actual station at all but aims to give the viewer information without unnecessary visual clutter. A schematic diagram of a chemical process uses symbols in place of detailed representations of the vessels, piping, valves, pumps, and other equipment that compose the system, thus emphasizing the functions of the individual elements and the interconnections among them and suppresses their physical details. In an electronic circuit d ...
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Sunlight
Sunlight is a portion of the electromagnetic radiation given off by the Sun, in particular infrared, visible, and ultraviolet light. On Earth, sunlight is scattered and filtered through Earth's atmosphere, and is obvious as daylight when the Sun is above the horizon. When direct solar radiation is not blocked by clouds, it is experienced as sunshine, a combination of bright light and radiant heat. When blocked by clouds or reflected off other objects, sunlight is diffused. Sources estimate a global average of between 164 watts to 340 watts per square meter over a 24-hour day; this figure is estimated by NASA to be about a quarter of Earth's average total solar irradiance. The ultraviolet radiation in sunlight has both positive and negative health effects, as it is both a requisite for vitamin D3 synthesis and a mutagen. Sunlight takes about 8.3 minutes to reach Earth from the surface of the Sun. A photon starting at the center of the Sun and changing direction eve ...
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Reflection (physics)
Reflection is the change in direction of a wavefront at an interface between two different media so that the wavefront returns into the medium from which it originated. Common examples include the reflection of light, sound and water waves. The ''law of reflection'' says that for specular reflection (for example at a mirror) the angle at which the wave is incident on the surface equals the angle at which it is reflected. In acoustics, reflection causes echoes and is used in sonar. In geology, it is important in the study of seismic waves. Reflection is observed with surface waves in bodies of water. Reflection is observed with many types of electromagnetic wave, besides visible light. Reflection of Very high frequency, VHF and higher frequencies is important for radio transmission and for radar. Even hard X-rays and gamma rays can be reflected at shallow angles with special "grazing" mirrors. Reflection of light Reflection of light is either ''Specular reflection, specular'' (mi ...
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Cloud Albedo
Cloud albedo is a measure of the albedo or reflectivity of a cloud. Clouds regulate the amount of solar radiation absorbed by a planet and its solar surface irradiance. Generally, increased cloud cover correlates to a higher albedo and a lower absorption of solar energy. Cloud albedo strongly influences the Earth's energy budget, accounting for approximately half of Earth's albedo. Cloud albedo depends on the total mass of water, the size and shape of the droplets or particles and their distribution in space. Thick clouds (such as stratocumulus) reflect a large amount of incoming solar radiation, translating to a high albedo. Thin clouds (such as cirrus) tend to transmit more solar radiation and, therefore, have a low albedo. Changes in cloud albedo caused by variations in cloud properties have a significant effect on global climate. Cloud condensation nuclei and cloud albedo On a microscopic scale, clouds are formed through the condensation of water on cloud condensation nucle ...
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Cloud Condensation Nuclei
Cloud condensation nuclei (CCNs), also known as cloud seeds, are small particles typically 0.2  µm, or one hundredth the size of a cloud droplet. CCNs are a unique subset of aerosols in the atmosphere on which water vapour condenses. This can affect the radiative properties of clouds and the overall atmosphere. Water requires a non-gaseous surface to make the transition from a vapour to a liquid; this process is called condensation. In the atmosphere of Earth, this surface presents itself as tiny solid or liquid particles called CCNs. When no CCNs are present, water vapour can be supercooled at about for 5–6 hours before droplets spontaneously form. This is the basis of the cloud chamber for detecting subatomic particles. The concept of CCN is used in cloud seeding, which tries to encourage rainfall by seeding the air with condensation nuclei. It has further been suggested that creating such nuclei could be used for marine cloud brightening, a climate engineering techni ...
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Sulfate Aerosols
The term sulfate aerosols is used for a suspension of fine solid particles of a sulfate or tiny droplets of a solution of a sulfate or of sulfuric acid (hydrogen sulfate). They are produced by chemical reactions in the atmosphere from gaseous precursors (with the exception of sea salt sulfate and gypsum dust particles). The two main sulfuric acid precursors are sulfur dioxide (SO2) from anthropogenic sources and volcanoes, and dimethyl sulfide (DMS) from biogenic sources, especially marine plankton. These aerosols can cause a cooling effect on earth. However the UNFCCC has noted that sulfate aerosols remain in the atmosphere for only a short amount of time in comparison to well-mixed greenhouse gases, and therefore their cooling is localized and temporary. Other side effects of sulfate aerosols in the environment include poor air quality.http://unfccc.int/essential_background/background_publications_htmlpdf/climate_change_information_kit/items/72.php UNFCC, Climate Change Informa ...
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Sulfur Dioxide
Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a toxic gas responsible for the odor of burnt matches. It is released naturally by volcanic activity and is produced as a by-product of copper extraction and the burning of sulfur- bearing fossil fuels. Structure and bonding SO2 is a bent molecule with ''C''2v symmetry point group. A valence bond theory approach considering just ''s'' and ''p'' orbitals would describe the bonding in terms of resonance between two resonance structures. The sulfur–oxygen bond has a bond order of 1.5. There is support for this simple approach that does not invoke ''d'' orbital participation. In terms of electron-counting formalism, the sulfur atom has an oxidation state of +4 and a formal charge of +1. Occurrence Sulfur dioxide is found on Earth and exists in very small concentrations and in the atmosphere at about 1 ppm. On other planets, ...
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Oxidation
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. There are two classes of redox reactions: * ''Electron-transfer'' – Only one (usually) electron flows from the reducing agent to the oxidant. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * ''Atom transfer'' – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidation reactions are commonly associated with the formation of oxides, other chemical species can serve the same function. In hydrogenation, C=C (and other) bonds ar ...
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