Borate Sulfates
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Borate Sulfates
Borate sulfates are mixed anion compounds containing separate borate and sulfate anions. They are distinct from the borosulfates The borosulfates are heteropoly anion compounds which have sulfate groups attached to boron atoms. Other possible terms are sulfatoborates or boron-sulfur oxides. The ratio of sulfate to borate reflects the degree of condensation. With (SO4)4sup>5 ... where the borate is linked to a sulfate via a common oxygen atom. List References {{Sulfates Borate sulfates ...
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Mixed Anion Compounds
Mixed anion compounds, heteroanionic materials or mixed anion materials are chemical compounds containing cations and more than one kind of anion. The compounds contain a single phase, rather than just a mixture. Use in materials science By having more than one anion, many more compounds can be made, and properties tuned to desirable values. In terms of optics, properties include laser damage threshold, refractive index, birefringence, absorption particularly in the ultraviolet or near infrared, non-linearity. Mechanical properties can include ability to grow a large crystal, ability to form a thin layer, strength, or brittleness. Thermal properties can include melting point, thermal stability, phase transition temperatures, Thermal expansion coefficient. For electrical properties, electric conductivity, band gap, superconducting transition temperature piezoelectricity, pyroelectricity, ferromagnetism, dielectric constant, charge-density wave transition can be adjusted. Pro ...
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Charlesite
Charlesite is a sulfate mineral of the ettringite group. Charlesite was named in 1945 after Dr. Charles Palache mineralogist and professor at Harvard University for his work on minerals. This mineral is extremely rare, and when it is found it is often in crystal (but not gem) form. Its crystals are soft hexagonal, that can vary in color.http://rruff.info/doclib/am/vol68/AM68_1033.pdf Handbook of Mineralogy Colors can range from clear to white, or even a pale yellow or pink. The brittle mineral's Mohs hardness is 2.5 with a specific gravity of 1.79. Though transparent to the eye the mineral has a white streak.http://webmineral.com/data/Charlesite.shtml#.Vl9UQuk0_wx WebMineral.com Occurrence Charlesite has only been found in a few specific locations in the world. The first was its place of discovery in Franklin Mine in Franklin, Sussex County, New Jersey. It was located immediately above the 800 level, about 15 feet into the ore from the hanging wall. The ore mostly consisted of ...
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Fontarnauite
Fontarnauite is a relatively recently described, rare sulfate, borate mineral with the chemical formula . It is found in an evaporite boron deposit. It coexists with other evaporite boron minerals, especially probertite. It is monoclinic, crystallizing in the space group ''P''21/''c''.García-Veigas, J., Rosell, L., Alcobé, X., Subias, I., Ortí, F., Gündoğan, İ., and Helvaci, C., 2010. Fontarnauite, a New Sulphate-Borate Mineral from the Emet Borate District (Turkey). Revista de la Sociedad Española de Mineralogía 13, 97-98 It was named for Ramon Fontarnau i Griera, a materials scientist of the University of Barcelona The University of Barcelona ( ca, Universitat de Barcelona, UB; ; es, link=no, Universidad de Barcelona) is a public university located in the city of Barcelona, Catalonia, in Spain. With 63,000 students, it is one of the biggest universities i .... References Borate minerals Sulfate minerals Sodium minerals Strontium minerals Monoclinic minera ...
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Sturmanite
Sturmanite is a rare sulfate mineral with the chemical formula Ca6 Fe3+2( SO4)2.5( B(OH)4)( OH)12 · 25 H2O. It crystallises in the tetragonal system and it has a Moh's hardness of 2.5. Sturmanite has a bright yellow to amber colour and falls in the ettringite group. It was named after Bozidar Darko Sturman (born 1937), Croatian-Canadian mineralogist and Curator Emeritus of Mineralogy, Royal Ontario Museum. Occurrence Sturmanite was first identified in 1983 and approved by the IMA in the same year. It was first found in the Black Rock Mine, Black Rock, Kalahari manganese field, Northern Cape Province, South Africa. It is found as flattened dipyramidal crystals on hematite and baryte. Sturmanite has also been identified in mines near the Black Rock Mine, such as the Wessel's and Perth mines, in the N'Chwaning mines, and near Lakargi Mountain in Russia. It is found as a rare secondary mineral embedded in manganese deposits and is associated with baryte, manganite, hausmann ...
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Hexagonal Crystal Family
In crystallography, the hexagonal crystal family is one of the six crystal families, which includes two crystal systems (hexagonal and trigonal) and two lattice systems (hexagonal and rhombohedral). While commonly confused, the trigonal crystal system and the rhombohedral lattice system are not equivalent (see section crystal systems below). In particular, there are crystals that have trigonal symmetry but belong to the hexagonal lattice (such as α-quartz). The hexagonal crystal family consists of the 12 point groups such that at least one of their space groups has the hexagonal lattice as underlying lattice, and is the union of the hexagonal crystal system and the trigonal crystal system. There are 52 space groups associated with it, which are exactly those whose Bravais lattice is either hexagonal or rhombohedral. __TOC__ Lattice systems The hexagonal crystal family consists of two lattice systems: hexagonal and rhombohedral. Each lattice system consists of one Bravais la ...
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Trigonal
In crystallography, the hexagonal crystal family is one of the six crystal families, which includes two crystal systems (hexagonal and trigonal) and two lattice systems (hexagonal and rhombohedral). While commonly confused, the trigonal crystal system and the rhombohedral lattice system are not equivalent (see section crystal systems below). In particular, there are crystals that have trigonal symmetry but belong to the hexagonal lattice (such as α-quartz). The hexagonal crystal family consists of the 12 point groups such that at least one of their space groups has the hexagonal lattice as underlying lattice, and is the union of the hexagonal crystal system and the trigonal crystal system. There are 52 space groups associated with it, which are exactly those whose Bravais lattice is either hexagonal or rhombohedral. __TOC__ Lattice systems The hexagonal crystal family consists of two lattice systems: hexagonal and rhombohedral. Each lattice system consists of one Bravais l ...
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Monoclinic Crystal System
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a parallelogram prism. Hence two pairs of vectors are perpendicular (meet at right angles), while the third pair makes an angle other than 90°. Bravais lattices Two monoclinic Bravais lattices exist: the primitive monoclinic and the base-centered monoclinic. For the base-centered monoclinic lattice, the primitive cell has the shape of an oblique rhombic prism;See , row mC, column Primitive, where the cell parameters are given as a1 = a2, α = β it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primitive cell below equals \frac \sqrt of the conventional cell above. Crystal classes The table below organ ...
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Borate
A borate is any of several boron oxyanions, negative ions consisting of boron and oxygen, such as orthoborate , metaborate , or tetraborate ; or any salt with such anions, such as sodium metaborate, and disodium tetraborate . The name also refers to certain functional groups in molecules consisting of boron and oxygen, and esters with such groups, such as triethyl orthoborate . Natural occurrence Borate ions occur, alone or with other anions, in many borate and borosilicate minerals such as borax, boracite, ulexite (boronatrocalcite) and colemanite. Borates also occur in seawater, where they make an important contribution to the absorption of low frequency sound in seawater. Borates also occur in plants, including almost all fruits. Anions The main borate anions are: * tetrahydroxyborate , found in sodium tetrahydroxyborate . * orthoborate , found in trisodium orthoborate * perborate , as in sodium perborate * metaborate or , found in sodium metaborate * diborate , f ...
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