Birkeland–Eyde Process
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Birkeland–Eyde Process
The Birkeland–Eyde process was one of the competing industrial processes in the beginning of nitrogen-based fertilizer production. It is a multi-step nitrogen fixation reaction that uses electrical arcs to react atmospheric nitrogen (N2) with oxygen (O2), ultimately producing nitric acid (HNO3) with water. The resultant nitric acid was then used as a source of nitrate (NO3−) in the reaction HNO3 + H2O -> H3O+ + NO3- which may take place in the presence of water or another proton acceptor. It was developed by Norwegian industrialist and scientist Kristian Birkeland along with his business partner Sam Eyde in 1903, based on a method used by Henry Cavendish in 1784. A factory based on the process was built in Rjukan and Notodden in Norway, combined with the building of large hydroelectric power facilities. The Birkeland–Eyde process is relatively inefficient in terms of energy consumption. Therefore, in the 1910s and 1920s, it was gradually replaced in Norway by a combination ...
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Rjukan Electric Arc Furnace
Rjukan () is a town and the administrative centre of Tinn municipality in Telemark, Norway. It is situated in Vestfjorddalen, between Møsvatn and Lake Tinn, and got its name after Rjukan Falls west of the town. The Tinn municipality council granted township status for Rjukan in 1996. The town has 3,386 inhabitants (January 2007). History Rjukan was formerly a significant industrial centre in Telemark, and the town was established between 1905 and 1916, when Norsk Hydro started saltpetre (fertilizer) production there. Rjukan was chosen because Rjukan Falls, a 104-metre waterfall, provided easy means of generating large quantities of electricity. The man with the idea to use the Rjukan falls was Sam Eyde, the founder of Hydro. It is estimated that he, together with A/S Rjukanfoss (later Norsk Hydro), used about two times the national budget of Norway to build the Rjukan power station as well as much of the surrounding town. Between 1907 and 1911, Norsk Hydro built wh ...
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Lime (material)
Lime is a calcium-containing inorganic material composed primarily of oxides and hydroxide, usually calcium oxide and/or calcium hydroxide. It is also the name for calcium oxide which occurs as a product of coal-seam fires and in altered limestone xenoliths in volcanic ejecta. The International Mineralogical Association recognizes lime as a mineral with the chemical formula of CaO. The word ''lime'' originates with its earliest use as building mortar and has the sense of ''sticking or adhering''. These materials are still used in large quantities as building and engineering materials (including limestone products, cement, concrete, and mortar), as chemical feedstocks, and for sugar refining, among other uses. Lime industries and the use of many of the resulting products date from prehistoric times in both the Old World and the New World. Lime is used extensively for wastewater treatment with ferrous sulfate. The rocks and minerals from which these materials are derived, typ ...
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Plate Column
A plate column (or tray column) is a chemical equipment used to carry out unit operations where it is necessary to transfer mass between a liquid phase and a gas phase. In other words, it is a particular gas-liquid contactor. The peculiarity of this gas-liquid contactor is that the gas comes in contact with liquid through different stages; each stage is delimited by two plates (except the stage at the top of the column and the stage at the bottom of the column). Some common applications of plate columns are distillation, gas-liquid absorption and liquid-liquid extraction. In general, plate columns are suitable for both continuous and batch operations. Fluid dynamics The feed to the column can be liquid, gas or gas and liquid at equilibrium. Inside the column there are always two phases: one gas phase and one liquid phase. The liquid phase flows downward through the column via gravity, while the gas phase flows upward. These two phases come in contact in correspondence of h ...
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Packed Bed
In chemical processing, a packed bed is a hollow tube, pipe, or other vessel that is filled with a packing material. The packing can be randomly filled with small objects like Raschig rings or else it can be a specifically designed structured packing. Packed beds may also contain catalyst particles or adsorbents such as zeolite pellets, granular activated carbon, etc. The purpose of a packed bed is typically to improve contact between two phases in a chemical or similar process. Packed beds can be used in a chemical reactor, a distillation process, or a scrubber, but packed beds have also been used to store heat in chemical plants. In this case, hot gases are allowed to escape through a vessel that is packed with a refractory material until the packing is hot. Air or other cool gas is then fed back to the plant through the hot bed, thereby pre-heating the air or gas feed. Applications Packed column In industry, a packed column is a type of packed bed used to perform s ...
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Fractional Distillation
Fractional distillation is the separation of a mixture into its component parts, or fractions. Chemical compounds are separated by heating them to a temperature at which one or more fractions of the mixture will vaporize. It uses distillation to fractionate. Generally the component parts have boiling points that differ by less than 25 °C (45 °F) from each other under a pressure of one atmosphere. If the difference in boiling points is greater than 25 °C, a simple distillation is typically used. It is used to refine crude oil. Laboratory setup Fractional distillation in a laboratory makes use of common laboratory glassware and apparatuses, typically including a Bunsen burner, a round-bottomed flask and a condenser, as well as the single-purpose fractionating column. As an example, consider the distillation of a mixture of water and ethanol. Ethanol boils at while water boils at . So, by heating the mixture, the most volatile component (ethanol) will concen ...
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Nitrogen Dioxide
Nitrogen dioxide is a chemical compound with the formula . It is one of several nitrogen oxides. is an intermediate in the industrial synthesis of nitric acid, millions of tons of which are produced each year for use primarily in the production of fertilizers. At higher temperatures it is a reddish-brown gas. It can be fatal if inhaled in large quantities. Nitrogen dioxide is a paramagnetic, bent molecule with C2v point group symmetry. It is included in the NOx family of atmospheric pollutants. Properties Nitrogen dioxide is a reddish-brown gas with a pungent, acrid odor above , becomes a yellowish-brown liquid below , and converts to the colorless dinitrogen tetroxide () below . The bond length between the nitrogen atom and the oxygen atom is 119.7  pm. This bond length is consistent with a bond order between one and two. Unlike ozone, O3, the ground electronic state of nitrogen dioxide is a doublet state, since nitrogen has one unpaired electron, which decreases ...
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Nitric Oxide
Nitric oxide (nitrogen oxide or nitrogen monoxide) is a colorless gas with the formula . It is one of the principal oxides of nitrogen. Nitric oxide is a free radical: it has an unpaired electron, which is sometimes denoted by a dot in its chemical formula In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, ... (•N=O or •NO). Nitric oxide is also a heteronuclear diatomic molecule, a class of molecules whose study spawned early modern molecular orbital theory, theories of chemical bonding. An important Reaction intermediate, intermediate in chemical industry, industrial chemistry, nitric oxide forms in combustion systems and can be generated by lightning in thunderstorms. In mammals, including humans, nitric oxide is a signaling molecule in many physiological and pathological pro ...
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Walther Nernst
Walther Hermann Nernst (; 25 June 1864 – 18 November 1941) was a German chemist known for his work in thermodynamics, physical chemistry, electrochemistry, and solid state physics. His formulation of the Nernst heat theorem helped pave the way for the third law of thermodynamics, for which he won the 1920 Nobel Prize in Chemistry. He is also known for developing the Nernst equation in 1887. Life and career Early years Nernst was born in Briesen in West Prussia (now Wąbrzeźno, Poland) to Gustav Nernst (1827–1888) and Ottilie Nerger (1833–1876). His father was a country judge. Nernst had three older sisters and one younger brother. His third sister died of cholera. Nernst went to elementary school at Graudenz. He studied physics and mathematics at the universities of Zürich, Berlin, Graz and Würzburg, where he received his doctorate 1887. In 1889, he finished his habilitation at University of Leipzig. Personal attributes It was said that Nernst was mechanically minde ...
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Julius Plücker
Julius Plücker (16 June 1801 – 22 May 1868) was a German mathematician and physicist. He made fundamental contributions to the field of analytical geometry and was a pioneer in the investigations of cathode rays that led eventually to the discovery of the electron. He also vastly extended the study of Lamé curves. Biography Early years Plücker was born at Elberfeld (now part of Wuppertal). After being educated at Düsseldorf and at the universities of Bonn, Heidelberg and Berlin he went to Paris in 1823, where he came under the influence of the great school of French geometers, whose founder, Gaspard Monge, had only recently died. In 1825 he returned to Bonn, and in 1828 was made professor of mathematics. In the same year he published the first volume of his ''Analytisch-geometrische Entwicklungen'', which introduced the method of "abridged notation". In 1831 he published the second volume, in which he clearly established on a firm and independent basis projective ...
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Lorentz Force
In physics (specifically in electromagnetism) the Lorentz force (or electromagnetic force) is the combination of electric and magnetic force on a point charge due to electromagnetic fields. A particle of charge moving with a velocity in an electric field and a magnetic field experiences a force of \mathbf = q\,\mathbf + q\,\mathbf \times \mathbf (in SI unitsIn SI units, is measured in teslas (symbol: T). In Gaussian-cgs units, is measured in gauss (symbol: G). See e.g. )The -field is measured in amperes per metre (A/m) in SI units, and in oersteds (Oe) in cgs units. ). It says that the electromagnetic force on a charge is a combination of a force in the direction of the electric field proportional to the magnitude of the field and the quantity of charge, and a force at right angles to the magnetic field and the velocity of the charge, proportional to the magnitude of the field, the charge, and the velocity. Variations on this basic formula describe the magnetic force on ...
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Electromagnet
An electromagnet is a type of magnet in which the magnetic field is produced by an electric current. Electromagnets usually consist of wire wound into a coil. A current through the wire creates a magnetic field which is concentrated in the hole in the center of the coil. The magnetic field disappears when the current is turned off. The wire turns are often wound around a magnetic core made from a ferromagnetic or ferrimagnetic material such as iron; the magnetic core concentrates the magnetic flux and makes a more powerful magnet. The main advantage of an electromagnet over a permanent magnet is that the magnetic field can be quickly changed by controlling the amount of electric current in the winding. However, unlike a permanent magnet that needs no power, an electromagnet requires a continuous supply of current to maintain the magnetic field. Electromagnets are widely used as components of other electrical devices, such as motors, generators, electromechanical solen ...
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