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Borafullerene
Borafullerenes are a class of heterofullerenes in which the element substituting for carbon is boron. They are also a member of the boron carbides Boron carbides are boron–carbon compounds. Boron carbide (B4C) B13C2 α-tetragonal boron α-tetragonal boron is a boron-rich isotropic boron carbide (B50C2). Borafullerenes Borafullerenes are a class of heterofullerenes in which the element ... class of materials that include Tetrabor (B4C). References Fullerenes {{chemistry-stub ...
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Boron Carbides
Boron carbides are boron–carbon compounds. Boron carbide (B4C) B13C2 α-tetragonal boron α-tetragonal boron is a boron-rich isotropic boron carbide (B50C2). Borafullerenes Borafullerenes are a class of heterofullerenes in which the element substituting for carbon is boron. See also * Crystal structure of boron-rich metal borides Metals, and specifically rare-earth elements, form numerous chemical complexes with boron. Their crystal structure and chemical bonding depend strongly on the metal element M and on its atomic ratio to boron. When B/M ratio exceeds 12, boron atom ... References Sources * * * * {{boron compounds Inorganic carbon compounds Boron compounds ...
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Heterofullerene
Heterofullerenes are classes of fullerenes, at least one carbon atom is replaced by another element. Based on spectroscopy, substitutions have been reported with boron (borafullerenes), nitrogen ( azafullerenes), oxygen, arsenic, germanium, phosphorus, silicon, iron, copper, nickel, rhodium and iridium Iridium is a chemical element with the symbol Ir and atomic number 77. A very hard, brittle, silvery-white transition metal of the platinum group, it is considered the second-densest naturally occurring metal (after osmium) with a density of .... Reports on isolated heterofullerenes are limited to those based on nitrogen and oxygen. References Fullerenes {{Chemistry-stub ...
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Carbon
Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent In chemistry, the valence (US spelling) or valency (British spelling) of an element is the measure of its combining capacity with other atoms when it forms chemical compounds or molecules. Description The combining capacity, or affinity of an ...—its atom making four electrons available to form covalent bond, covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon makes up only about 0.025 percent of Earth's crust. Three Isotopes of carbon, isotopes occur naturally, Carbon-12, C and Carbon-13, C being stable, while Carbon-14, C is a radionuclide, decaying with a half-life of about 5,730 years. Carbon is one of the Timeline of chemical element discoveries#Ancient discoveries, few elements known since antiquity. Carbon is the 15th Abundance of elements in Earth's crust, most abundant element in the Earth's crust, and the Abundance of the c ...
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Boron
Boron is a chemical element with the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the ''boron group'' it has three valence electrons for forming covalent bonds, resulting in many compounds such as boric acid, the mineral borax, sodium borate, and the ultra-hard crystals of boron carbide and boron nitride. Boron is synthesized entirely by cosmic ray spallation and supernovae and not by stellar nucleosynthesis, so it is a low-abundance element in the Solar System and in the Crust (geology), Earth's crust. It constitutes about 0.001 percent by weight of Earth's crust. It is concentrated on Earth by the water-solubility of its more common naturally occurring compounds, the borate minerals. These are mined industrially as evaporites, such as borax and kernite. The largest known deposits are in Turkey, the largest producer of boron minerals. Elemental b ...
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Tetrabor
Boron carbide (chemical formula approximately B4C) is an extremely hard boron–carbon ceramic, a covalent material used in tank armor, bulletproof vests, engine sabotage powders, as well as numerous industrial applications. With a Vickers hardness of >30 GPa, it is one of the hardest known materials, behind cubic boron nitride and diamond. History Boron carbide was discovered in the 19th century as a by-product of reactions involving metal borides, but its chemical formula was unknown. It was not until the 1930s that the chemical composition was estimated as B4C. Controversy remained as to whether or not the material had this exact 4:1 stoichiometry, as, in practice the material is always slightly carbon-deficient with regard to this formula, and X-ray crystallography shows that its structure is highly complex, with a mixture of C-B-C chains and B12 icosahedra. These features argued against a very simple exact B4C empirical formula. Because of the B12 structural unit, the ...
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