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Boilover
A boilover (or boil-over) is an extremely hazardous phenomenon in which a layer of water under a pool fire (e.g., an open-top Storage tank, tank fire) starts boiling, which results in a significant increase in fire intensity accompanied by violent expulsion of burning fluid to the surrounding areas. Boilover can only occur if the liquid fluid is a mixture of different chemical species with sufficiently diverse boiling points, although a so-called ''thin-layer'' ''boilover'' – a far less hazardous phenomenon – can arise from any water-immiscible liquid fuel. Petroleum, Crude oil, kerosene and some Diesel fuel, diesel oils are examples of fuels giving rise to boilover. Boilovers at industrial scale are rare but can lead to serious plant damage. Given the sudden and not easily predictable onset of the phenomenon, fatalities can occur, especially among firefighters and bystanders that have not been made to leave the area. ''Slopover'' and ''frothover'' are phenomena similar to bo ...
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Pool Fire
A pool fire is a type of diffusion flame where a layer of volatile liquid fuel is evaporating and burning. The fuel layer can be either on a horizontal solid substrate or floating on a higher-density liquid, usually water. Pool fires are an important scenario in fire process safety and combustion science, as large amounts of liquid fuels are stored and transported by different industries. Physical properties The most important physical parameter describing a pool fire is the heat release rate, which determines the minimum safe distance needed to avoid burns from thermal radiation. The heat release rate is limited by the rate of evaporation of the fuel, as the combustion reaction takes place in the gas phase. The evaporation rate, in turn, is determined by other physical parameters, such as the depth, surface area and shape of the pool, as well as the fuel boiling point, heat of vaporization, heat of combustion, thermal conductivity and others. A feedback loop exists between the he ...
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Process Safety
Process safety is an interdisciplinary engineering domain focusing on the study, prevention, and management of large-scale fires, explosions and chemical accidents (such as toxic gas clouds) in process plants or other facilities dealing with hazardous materials, such as refineries and oil and gas ( onshore and offshore) production installations. Thus, process safety is generally concerned with the prevention of, control of, mitigation of and recovery from unintentional hazardous materials releases that can have a serious effect to people (onsite and offsite), plant and/or the environment. Definition and scope The American Petroleum Institute defines process safety as follows: A disciplined framework for managing the integrity of hazardous operating systems and processes by applying good design principles, engineering, and operating and maintenance practices. It deals with the prevention and control of events that have the potential to release hazardous materials or energy. Such ...
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Gasoline
Gasoline ( North American English) or petrol ( Commonwealth English) is a petrochemical product characterized as a transparent, yellowish, and flammable liquid normally used as a fuel for spark-ignited internal combustion engines. When formulated as a fuel for engines, gasoline is chemically composed of organic compounds derived from the fractional distillation of petroleum and later chemically enhanced with gasoline additives. It is a high-volume profitable product produced in crude oil refineries. The ability of a particular gasoline blend to resist premature ignition (which causes knocking and reduces efficiency in reciprocating engines) is measured by its octane rating. Tetraethyl lead was once widely used to increase the octane rating but is not used in modern automotive gasoline due to the health hazard. Aviation, off-road motor vehicles, and racing car engines still use leaded gasolines. Other substances are frequently added to gasoline to improve chemical st ...
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Viscosity
Viscosity is a measure of a fluid's rate-dependent drag (physics), resistance to a change in shape or to movement of its neighboring portions relative to one another. For liquids, it corresponds to the informal concept of ''thickness''; for example, syrup has a higher viscosity than water. Viscosity is defined scientifically as a force multiplied by a time divided by an area. Thus its SI units are newton-seconds per metre squared, or pascal-seconds. Viscosity quantifies the internal friction, frictional force between adjacent layers of fluid that are in relative motion. For instance, when a viscous fluid is forced through a tube, it flows more quickly near the tube's center line than near its walls. Experiments show that some stress (physics), stress (such as a pressure difference between the two ends of the tube) is needed to sustain the flow. This is because a force is required to overcome the friction between the layers of the fluid which are in relative motion. For a tube ...
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National Fire Protection Association
The National Fire Protection Association (NFPA) is a U.S.-based international nonprofit organization devoted to eliminating death, injury, property damage, and economic loss due to fire, electrical, and related hazards. , the NFPA claims to have 50,000 members and 9,000 volunteers working with the organization through its 250 technical committees. History In 1895, a Committee on Automatic Sprinkler Protection was formed in Massachusetts by men affiliated with several fire insurance companies and a pipe manufacturer to develop a uniform standard for the design and installation of fire sprinkler systems. At the time, there were nine such standards in effect within of Boston, Massachusetts, and such diversity was causing great difficulties for plumbers working in the New England New England is a region consisting of six states in the Northeastern United States: Connecticut, Maine, Massachusetts, New Hampshire, Rhode Island, and Vermont. It is bordered by the state of New Y ...
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Journal Of Loss Prevention In The Process Industries
A journal, from the Old French ''journal'' (meaning "daily"), may refer to: *Bullet journal, a method of personal organization *Diary, a record of personal secretive thoughts and as open book to personal therapy or used to feel connected to oneself. A record of what happened over the course of a day or other period *Daybook, also known as a general journal, a daily record of financial transactions *Logbook, a record of events important to the operation of a vehicle, facility, or otherwise *Transaction log, a chronological record of data processing *Travel journal, a record of the traveller's experience during the course of their journey In publishing, ''journal'' can refer to various periodicals or serials: *Academic journal, an academic or scholarly periodical **Scientific journal, an academic journal focusing on science **Medical journal, an academic journal focusing on medicine **Law review, a professional journal focusing on legal interpretation *Magazine, non-academic or scho ...
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Institution Of Chemical Engineers
The Institution of Chemical Engineers (IChemE) is a global professional engineering institution with 30,000 members in 114 countries. It was founded in 1922 and awarded a Royal Charter in 1957. The Institution has offices in Rugby, Warwickshire, Rugby, Melbourne, Wellington, New Zealand and Kuala Lumpur. History In 1881, George E. Davis proposed the formation of a Society of Chemical Engineers, but instead the Society of Chemical Industry (SCI) was formed. The First World War required a huge increase in chemical production to meet the needs of the munitions and its supply industries, including a twenty-fold increase in explosives. This brought a number of chemical engineers into high positions within the Ministry of Munitions, notably K. B. Quinan, Frederic Nathan and Arthur Duckham. The increased public perception of chemical engineers renewed the interest in a society, and in 1918 John Hinchley, who was a Council Member of the SCI, petitioned it to form a Chemical Engineers ...
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Loss Prevention Bulletin
Loss may refer to: *Economic loss *Grief, an emotional response to loss **Animal loss, grief over the loss of an animal Mathematics, science, and technology * Angular misalignment loss, power loss caused by the deviation from optimum angular alignment * Bridging loss, the loss that results when an impedance is connected across a transmission line * Coupling loss, the loss that occurs when energy is transferred from one circuit, optical device, or medium to another *Insertion loss, the decrease in transmitted signal power resulting from the insertion of a device in a transmission line or optical fiber *Dielectric loss, a dielectric material's inherent dissipation of electromagnetic energy *Loss function, in statistics, a function representing the cost associated with an event *Path loss, the attenuation undergone by an electromagnetic wave in transit from a transmitter to a receiver ** Free-space path loss, the loss in signal strength that would result if all influences were suffi ...
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Nucleation
In thermodynamics, nucleation is the first step in the formation of either a new Phase (matter), thermodynamic phase or Crystal structure, structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically defined to be the process that determines how long an observer has to wait before the new phase or self-organized structure appears. For example, if a volume of water is cooled (at atmospheric pressure) significantly below 0°C, it will tend to Freezing, freeze into ice, but volumes of water cooled only a few degrees below 0°C often stay completely free of ice for long periods (supercooling). At these conditions, nucleation of ice is either slow or does not occur at all. However, at lower temperatures nucleation is fast, and ice crystals appear after little or no delay. Nucleation is a common mechanism which generates first-order phase transitions, and it is the start of the process of forming a new thermodynamic phase. In contrast, new phas ...
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Explosive Boiling
In physical chemistry, explosive boiling or phase explosion is a process in which a superheated metastable liquid undergoes an explosive liquid–vapor phase transition into a stable two-phase state because of a massive homogeneous nucleation of vapor bubbles. This concept was pioneered by M. M. Martynyuk in 1976 and then later advanced by Fucke and Seydel. Mechanism Explosive boiling can be best described by a pressure–temperature (''p''–''T'') phase diagram. The figure on right shows a typical ''p''–''T'' phase diagram of a substance. The binodal line or the coexistence curve is a thermodynamic state where at that specific temperature and pressure, liquid and vapor can coexist. The spinodal line on right is the boundary of absolute instability of a solution to decomposition into multiple phases. A typical heating process is shown in red. If the heating process is relatively slow, the liquid has enough time to relax to an equilibrium state, the liquid follows the binodal ...
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Superheated Water
Superheated water is liquid water under pressure at temperatures between the usual boiling point, and the critical temperature, . It is also known as "subcritical water" or "pressurized hot water". Superheated water is stable because of overpressure that raises the boiling point, or by heating it in a sealed vessel with a headspace, where the liquid water is in equilibrium with vapour at the saturated vapor pressure. This is distinct from the use of the term superheating to refer to water at atmospheric pressure above its normal boiling point, which has not boiled due to a lack of nucleation sites (sometimes experienced by heating liquids in a microwave). Many of water's anomalous properties are due to very strong hydrogen bonding. Over the superheated temperature range the hydrogen bonds break, changing the properties more than usually expected by increasing temperature alone. Water becomes less polar and behaves more like an organic solvent such as methanol or ethanol. Solubil ...
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