Argyrotype
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Argyrotype
Argyrotype is an iron-based silver printing process that produces brown images on plain paper. It is an alternative process derived from the argentotype, kallitype, and Van Dyke processes of the 19th century, but has greater simplicity, improved image stability, and longer sensitizer shelf-life.Mike Ware It was developed by Mike Ware. While this process may not have the permanence of other processes such as platinum or palladium printing, it is much less expensive and more user friendly. The core resource used is silver sulphamate (NH2SO3Ag) which can be prepared on site from sulphamic acid. The sensitizer used is very slow, so printing must be by contact with a large format negative, using an ultraviolet Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nanometer, nm (with a corresponding frequency around 30 Hertz, PHz) to 400 nm (750 Hertz, THz), shorter than that of visible light, but longer than ... lamp or sunlight. As w ...
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Kallitype
Kallitype is a process for making photographic prints. Patented in 1889 by W. W. J. Nicol (1855-1929), the Kallitype print is an iron-silver process. A chemical process similar to the Van Dyke brown based on the use of a combination of ferric and silver salts. While Van Dyke brown and argyrotype use ferric ammonium citrate, the light-sensitive element used for the Kallitype is ferric oxalate. The use of ferric oxalate allows for both extended shadow definition (higher DMAX) and contrast control. Many developing solutions can be used to give a different image color (brown, sepia, blue, maroon and black). Kallitype images generally have a richer tonal range than the cyanotype. These prints were popular in the 19th century, and then their popularity faded away. Sometimes known as "the poor man's platinum print", when the image is toned in platinum or palladium the result is nearly chemically identical to a true Platinotype. It is believed that many Kallitypes were passed off as true ...
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Alternative Process
{{unsourced, date= March 2021 The term alternative process refers to any non-traditional or non-commercial photographic printing process. Currently the standard analog photographic printing process is the gelatin silver process, and standard digital processes include the pigment print, and digital laser exposures on traditional color photographic paper. Alternative processes are often called historical, or non-silver processes. Most of these processes were invented over 100 years ago and were used by early photographers. Many contemporary photographers are revisiting alternative processes and applying new technologies (the digital negative) and practices to these techniques. Examples *Caffenol *Daguerreotype *Gum bichromate and other Pigmented Dichromated Colloids which are used to directly generate a photographic print * Platinum Process and Palladium Process * Carbon print and various similar processes which use a non-sensitive intermediate layer to generate a photographic ...
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Mike Ware (photographer)
Michael J. Ware (born 1939, Bromley) is a chemist and photographer, known for his work in alternative photographic processes, earlier methods of printing photographic images that were succeeded by the more common silver-gelatin used today. In the Present, Ware acts as a consultant, most recently on the history and development of the platinotype and palladium processes. His has also written about chemistry's influence on the history of photography. Early life and education Ware was born in 1939 in Bromley. He earned his Ph.D. at the University of Oxford in 1965. His thesis was ''The vibrational spectra of some inorganic complexes.'' Awards and honours * 1982 Fellow of the Royal Society of Chemistry * 1990 Hood Medal The Royal Photographic Society of Great Britain, commonly known as the Royal Photographic Society (RPS), is one of the world's oldest photographic societies. It was founded in London, England, in 1853 as the Photographic Society of London with ..., awarded by t ...
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Platinum Printing
Platinum is a chemical element with the symbol Pt and atomic number 78. It is a dense, malleable, ductile, highly unreactive, precious, silverish-white transition metal. Its name originates from Spanish , a diminutive of "silver". Platinum is a member of the platinum group of elements and group 10 of the periodic table of elements. It has six naturally occurring isotopes. It is one of the rarer elements in Earth's crust, with an average abundance of approximately 5 μg/kg. It occurs in some nickel and copper ores along with some native deposits, mostly in South Africa, which accounts for ~80% of the world production. Because of its scarcity in Earth's crust, only a few hundred tonnes are produced annually, and given its important uses, it is highly valuable and is a major precious metal commodity. Platinum is one of the least reactive metals. It has remarkable resistance to corrosion, even at high temperatures, and is therefore considered a noble metal. Conseque ...
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Palladium Printing
Palladium is a chemical element with the symbol Pd and atomic number 46. It is a rare and lustrous silvery-white metal discovered in 1803 by the English chemist William Hyde Wollaston. He named it after the asteroid Pallas, which was itself named after the epithet of the Greek goddess Athena, acquired by her when she slew Pallas. Palladium, platinum, rhodium, ruthenium, iridium and osmium form a group of elements referred to as the platinum group metals (PGMs). They have similar chemical properties, but palladium has the lowest melting point and is the least dense of them. More than half the supply of palladium and its congener platinum is used in catalytic converters, which convert as much as 90% of the harmful gases in automobile exhaust (hydrocarbons, carbon monoxide, and nitrogen dioxide) into nontoxic substances (nitrogen, carbon dioxide and water vapor). Palladium is also used in electronics, dentistry, medicine, hydrogen purification, chemical applications, groundw ...
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Silver Sulphamate
Silver is a chemical element with the Symbol (chemistry), symbol Ag (from the Latin ', derived from the Proto-Indo-European wikt:Reconstruction:Proto-Indo-European/h₂erǵ-, ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, white, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. The metal is found in the Earth's crust in the pure, free elemental form ("native silver"), as an alloy with gold and other metals, and in minerals such as argentite and chlorargyrite. Most silver is produced as a byproduct of copper, gold, lead, and zinc Refining (metallurgy), refining. Silver has long been valued as a precious metal. Silver metal is used in many bullion coins, sometimes bimetallism, alongside gold: while it is more abundant than gold, it is much less abundant as a native metal. Its purity is typically measured on a per-mille basis; a 94%-pure alloy is described as "0.940 fine". As one of th ...
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Sulphamic Acid
Sulfamic acid, also known as amidosulfonic acid, amidosulfuric acid, aminosulfonic acid, sulphamic acid and sulfamidic acid, is a molecular compound with the formula H3NSO3. This colourless, water-soluble compound finds many applications. Sulfamic acid melts at 205 °C before decomposing at higher temperatures to water, sulfur trioxide, sulfur dioxide and nitrogen. Sulfamic acid (H3NSO3) may be considered an intermediate compound between sulfuric acid (H2SO4), and sulfamide (H4N2SO2), effectively replacing a hydroxyl (–OH) group with an amine (–NH2) group at each step. This pattern can extend no further in either direction without breaking down the sulfonyl (–SO2–) moiety. Sulfamates are derivatives of sulfamic acid. Production Sulfamic acid is produced industrially by treating urea with a mixture of sulfur trioxide and sulfuric acid (or oleum). The conversion is conducted in two stages, the first being sulfamation: :OC(NH2)2 + SO3 → OC(NH2)(NHSO3H) : ...
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Large Format
Large format refers to any imaging format of or larger. Large format is larger than "medium format", the or size of Hasselblad, Mamiya, Rollei, Kowa, and Pentax cameras (using 120- and 220-roll film), and much larger than the frame of 35 mm format. The main advantage of a large format, film or digital, is a higher resolution at the same pixel pitch, or the same resolution with larger pixels or grains which allows each pixel to capture more light enabling exceptional low-light capture. A 4×5 inch image (12.903 mm²) has about 15 times the area, and thus 15× the total resolution, of a 35 mm frame (864 mm²). Large format cameras were some of the earliest photographic devices, and before enlargers were common, it was normal to just make 1:1 contact prints from a 4×5, 5×7, or 8×10-inch negative. Formats The most common large format is 4×5 inches (10.2x12.7 cm), which was the size used by cameras like the Graflex Speed Graphic and Crown Gr ...
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Ultraviolet
Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nanometer, nm (with a corresponding frequency around 30 Hertz, PHz) to 400 nm (750 Hertz, THz), shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight, and constitutes about 10% of the total electromagnetic radiation output from the Sun. It is also produced by electric arcs and specialized lights, such as mercury-vapor lamps, tanning lamps, and black lights. Although long-wavelength ultraviolet is not considered an ionizing radiation because its photons lack the energy to ionization, ionize atoms, it can cause chemical reactions and causes many substances to glow or fluorescence, fluoresce. Consequently, the chemical and biological effects of UV are greater than simple heating effects, and many practical applications of UV radiation derive from its interactions with organic molecules. Short-wave ultraviolet light damages DNA and sterilizes surf ...
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