Anderson Impurity Model
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Anderson Impurity Model
The Anderson impurity model, named after Philip Warren Anderson, is a Hamiltonian that is used to describe magnetic impurities embedded in metals. It is often applied to the description of Kondo effect-type problems, such as heavy fermion systems and Kondo insulators. In its simplest form, the model contains a term describing the kinetic energy of the conduction electrons, a two-level term with an on-site Coulomb repulsion that models the impurity energy levels, and a hybridization term that couples conduction and impurity orbitals. For a single impurity, the Hamiltonian takes the form :H = \sum_\epsilon_k c^_c_ + \sum_\epsilon_ d^_d_ + Ud^_d_d^_d_ + \sum_V_k(d^_c_ + c^_d_), where the c operator is the annihilation operator of a conduction electron, and d is the annihilation operator for the impurity, k is the conduction electron wavevector, and \sigma labels the spin. The on–site Coulomb repulsion is U, and V gives the hybridization. Regimes The model yields several reg ...
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Philip Warren Anderson
Philip Warren Anderson (December 13, 1923 – March 29, 2020) was an American theoretical physicist and Nobel laureate. Anderson made contributions to the theories of localization, antiferromagnetism, symmetry breaking (including a paper in 1962 discussing symmetry breaking in particle physics, leading to the development of the Standard Model around 10 years later), and high-temperature superconductivity, and to the philosophy of science through his writings on emergent phenomena. Anderson is also responsible for naming the field of physics that is now known as condensed matter physics. Education and early life Anderson was born in Indianapolis, Indiana, and grew up in Urbana, Illinois. His father, Harry Warren Anderson, was a professor of plant pathology at the University of Illinois at Urbana; his maternal grandfather was a mathematician at Wabash College, where Anderson's father studied; and his maternal uncle was a Rhodes Scholar who became a professor of English, also at ...
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Fermi Level
The Fermi level of a solid-state body is the thermodynamic work required to add one electron to the body. It is a thermodynamic quantity usually denoted by ''µ'' or ''E''F for brevity. The Fermi level does not include the work required to remove the electron from wherever it came from. A precise understanding of the Fermi level—how it relates to electronic band structure in determining electronic properties, how it relates to the voltage and flow of charge in an electronic circuit—is essential to an understanding of solid-state physics. In band structure theory, used in solid state physics to analyze the energy levels in a solid, the Fermi level can be considered to be a hypothetical energy level of an electron, such that at thermodynamic equilibrium this energy level would have a ''50% probability of being occupied at any given time''. The position of the Fermi level in relation to the band energy levels is a crucial factor in determining electrical properties. The Fermi le ...
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Anderson Localization
In condensed matter physics, Anderson localization (also known as strong localization) is the absence of diffusion of waves in a ''disordered'' medium. This phenomenon is named after the American physicist P. W. Anderson, who was the first to suggest that electron localization is possible in a lattice potential, provided that the degree of randomness (disorder) in the lattice is sufficiently large, as can be realized for example in a semiconductor with impurities or defects. Anderson localization is a general wave phenomenon that applies to the transport of electromagnetic waves, acoustic waves, quantum waves, spin waves, etc. This phenomenon is to be distinguished from weak localization, which is the precursor effect of Anderson localization (see below), and from Mott localization, named after Sir Nevill Mott, where the transition from metallic to insulating behaviour is ''not'' due to disorder, but to a strong mutual Coulomb repulsion of electrons. Introduction In the or ...
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Kondo Model
The Kondo model (sometimes referred to as the s-d model) is a model for a single localized quantum impurity coupled to a large reservoir of delocalized and noninteracting electrons. The quantum impurity is represented by a spin-1/2 particle, and is coupled to a continuous band of noninteracting electrons by an antiferromagnetic exchange coupling J. The Kondo model is used as a model for metals containing magnetic impurities, as well as quantum dot systems. Kondo Hamiltonian The Kondo Hamiltonian is given by :H = \sum_ \epsilon_ c^_c_ - J \mathbf\cdot \mathbf where \mathbf is the spin-1/2 operator representing the impurity, and :\mathbf = \sum_ c^_ \mathbf_c_ is the local spin-density of the noninteracting band at the impurity site ( \mathbf are the Pauli matrices). In the Kondo problem, J 0). The Kondo model is intimately related to the Anderson impurity model, as can be shown by Schrieffer–Wolff transformation. See also *Anderson impurity model *Kondo effect In physic ...
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Number Operator
In quantum mechanics, for systems where the total number of particles may not be preserved, the number operator is the observable that counts the number of particles. The number operator acts on Fock space. Let :, \Psi\rangle_\nu=, \phi_1,\phi_2,\cdots,\phi_n\rangle_\nu be a Fock state, composed of single-particle states , \phi_i\rangle drawn from a basis of the underlying Hilbert space of the Fock space. Given the corresponding creation and annihilation operators a^(\phi_i) and a(\phi_i)\, we define the number operator by :\hat \ \stackrel\ a^(\phi_i)a(\phi_i) and we have :\hat, \Psi\rangle_\nu=N_i, \Psi\rangle_\nu where N_i is the number of particles in state , \phi_i\rangle. The above equality can be proven by noting that :\begin a(\phi_i) , \phi_1,\phi_2,\cdots,\phi_,\phi_i,\phi_,\cdots,\phi_n\rangle_\nu &=& \sqrt , \phi_1,\phi_2,\cdots,\phi_,\phi_,\cdots,\phi_n\rangle_\nu \\ a^(\phi_i) , \phi_1,\phi_2,\cdots,\phi_,\phi_,\cdots,\phi_n\rangle_\nu &=& \sqrt , \phi_1,\phi ...
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Carbon Nanotube Quantum Dot
A carbon nanotube quantum dot (CNT QD) is a small region of a carbon nanotube in which electrons are confined. Formation A CNT QD is formed when electrons are confined to a small region within a carbon nanotube. This is normally accomplished by application of a voltage to a gate electrode, dragging the valence band of the CNT down in energy, thereby causing electrons to pool in a region in the vicinity of the electrode. Experimentally this is accomplished by laying a CNT on a silicon dioxide surface, sitting on a doped silicon wafer. This can be done by chemical vapor deposition using carbon monoxide. The silicon wafer serves as the gate electrode. Metallic leads can then be laid over the nanotube in order to connect the CNT QD up to an electrical circuit. Electronic structure The CNT QD has interesting properties as a result of the strong correlation between the confined electrons. In addition to this the electrons possess orbital angular momentum, as is characteristic of CNT ...
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Special Unitary Group
In mathematics, the special unitary group of degree , denoted , is the Lie group of unitary matrices with determinant 1. The more general unitary matrices may have complex determinants with absolute value 1, rather than real 1 in the special case. The group operation is matrix multiplication. The special unitary group is a normal subgroup of the unitary group , consisting of all unitary matrices. As a compact classical group, is the group that preserves the standard inner product on \mathbb^n. It is itself a subgroup of the general linear group, \operatorname(n) \subset \operatorname(n) \subset \operatorname(n, \mathbb ). The groups find wide application in the Standard Model of particle physics, especially in the electroweak interaction and in quantum chromodynamics. The groups are important in quantum computing, as they represent the possible quantum logic gate operations in a quantum circuit with n qubits and thus 2^n basis states. (Alternatively, the more genera ...
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Hill Limit (solid-state)
In solid-state physics, the Hill limit is a critical distance defined in a lattice of actinide or rare-earth atoms. These atoms own partially filled 4f or 5f levels in their valence shell and are therefore responsible for the main interaction between each atom and its environment. In this context, the hill limit r_H is defined as twice the radius of the f-orbital. Therefore, if two atoms of the lattice are separate by a distance greater than the Hill limit, the overlap of their f-orbital becomes negligible. A direct consequence is the absence of hopping for the f electrons, ie their localization on the ion sites of the lattice. Localized f electrons lead to paramagnetic materials since the remaining unpaired spins are stuck in their orbitals. However, when the rare-earth lattice (or a single atom) is embedded in a metallic one (intermetallic compound), interactions with the conduction band allow the f electrons to move through the lattice even for interatomic distances above the Hill ...
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Atomic Orbital
In atomic theory and quantum mechanics, an atomic orbital is a function describing the location and wave-like behavior of an electron in an atom. This function can be used to calculate the probability of finding any electron of an atom in any specific region around the atom's nucleus. The term ''atomic orbital'' may also refer to the physical region or space where the electron can be calculated to be present, as predicted by the particular mathematical form of the orbital. Each orbital in an atom is characterized by a set of values of the three quantum numbers , , and , which respectively correspond to the electron's energy, angular momentum, and an angular momentum vector component (magnetic quantum number). Alternative to the magnetic quantum number, the orbitals are often labeled by the associated harmonic polynomials (e.g., ''xy'', ). Each such orbital can be occupied by a maximum of two electrons, each with its own projection of spin m_s. The simple names s orbital, p orb ...
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Spin (physics)
Spin is a conserved quantity carried by elementary particles, and thus by composite particles (hadrons) and atomic nucleus, atomic nuclei. Spin is one of two types of angular momentum in quantum mechanics, the other being ''orbital angular momentum''. The orbital angular momentum operator is the quantum-mechanical counterpart to the classical angular momentum of orbital revolution and appears when there is periodic structure to its wavefunction as the angle varies. For photons, spin is the quantum-mechanical counterpart of the Polarization (waves), polarization of light; for electrons, the spin has no classical counterpart. The existence of electron spin angular momentum is inferred from experiments, such as the Stern–Gerlach experiment, in which silver atoms were observed to possess two possible discrete angular momenta despite having no orbital angular momentum. The existence of the electron spin can also be inferred theoretically from the spin–statistics theorem and from th ...
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Hamiltonian (quantum Mechanics)
Hamiltonian may refer to: * Hamiltonian mechanics, a function that represents the total energy of a system * Hamiltonian (quantum mechanics), an operator corresponding to the total energy of that system ** Dyall Hamiltonian, a modified Hamiltonian with two-electron nature ** Molecular Hamiltonian, the Hamiltonian operator representing the energy of the electrons and nuclei in a molecule * Hamiltonian (control theory), a function used to solve a problem of optimal control for a dynamical system * Hamiltonian path, a path in a graph that visits each vertex exactly once * Hamiltonian group, a non-abelian group the subgroups of which are all normal * Hamiltonian economic program, the economic policies advocated by Alexander Hamilton, the first United States Secretary of the Treasury See also * Alexander Hamilton (1755 or 1757–1804), American statesman and one of the Founding Fathers of the US * Hamilton (other) Hamilton may refer to: People * Hamilton (name), a common ...
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Wavevector
In physics, a wave vector (or wavevector) is a vector used in describing a wave, with a typical unit being cycle per metre. It has a magnitude and direction. Its magnitude is the wavenumber of the wave (inversely proportional to the wavelength), and its direction is perpendicular to the wavefront. In isotropic media, this is also the direction of wave propagation. A closely related vector is the angular wave vector (or angular wavevector), with a typical unit being radian per metre. The wave vector and angular wave vector are related by a fixed constant of proportionality, 2π radians per cycle. It is common in several fields of physics to refer to the angular wave vector simply as the ''wave vector'', in contrast to, for example, crystallography. It is also common to use the symbol ''k'' for whichever is in use. In the context of special relativity, ''wave vector'' can refer to a four-vector, in which the (angular) wave vector and (angular) frequency are combined. Def ...
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