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Alkynols
Alkynols (''hydroxyalkynes'') are organic chemical compounds derived from alkynes and are among the alcohols. Thus, as structural features, they have a C≡C triple bond and a hydroxy group. They are not identical to the ynols. Some alkynols play a role as intermediates in the chemical industry. Compounds in this group include propargyl alcohol, 3-butyn-1-ol, and 5-hexyn-1-ol. Synthesis Alkynols may be formed by the alkynylation of carbonyl compounds, usually in liquid ammonia. Literature * Allinger, Cava, de Jongh, Johnson, Lebel, Stevens: ''Organische Chemie'', 1. Auflage, Walter de Gruyter, Berlin 1980, , p. 749. * Beyer / Walter: ''Lehrbuch der Organischen Chemie'', 19. Auflage, S. Hirzel Verlag, Stuttgart 1981, , pp. 98–99, 122. * K. Peter C. Vollhardt, Neil E. Schore Neil E. Schore is an American chemist and former associate professor of organic chemistry and Vice Chair of Chemistry at the University of California, Davis. He is also the co-author of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ynol
In organic chemistry, an alkynol (shortened to ynol) is an alkyne with a hydroxyl group affixed to one of the two carbon atoms composing the triple bond (). The deprotonated anions of ynols are known as ''ynolates''. An ynol with hydroxyl groups on both sides of its triple bond is known as an ynediol; only one ynediol, acetylenediol, exists. Ynolates Ynolates are chemical compounds with a negatively charged oxygen atom attached to an alkyne functionality. They were first synthesized in 1975 by Schöllkopf and Hoppe via the ''n''-butyllithium fragmentation of 3,4-diphenylisoxazole. Synthetically, they behave as ketene precursors or synthons. Ynol–ketene tautomerism Ynols can interconvert with ketenes, much like enols can with aldehydes and ketones. The ynol tautomer is usually unstable, does not survive long, and changes into the ketene. This is because oxygen is more electronegative than carbon and thus forms stronger bonds. For instance, ethynol quickly inter ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Propargyl Alcohol
Propargyl alcohol, or 2-propyn-1-ol, is an organic compound with the chemical formula, formula C3H4O. It is the simplest stable Alcohol (chemistry), alcohol containing an alkyne functional group. Propargyl alcohol is a colorless viscous liquid that is miscible with water and most polar organic solvents. Reactions and applications Propargyl alcohol polymerizes with heating or treatment with base (chemistry), base. It is used as a corrosion inhibitor, a metal complex solution, a solvent stabilizer and an electroplating brightener additive. It is also used as an intermediate in organic synthesis. Secondary alcohol, Secondary and Tertiary alcohol, tertiary substituted propargylic alcohols undergo catalyzed rearrangement reactions to form carbonyl#α,β-Unsaturated carbonyl compounds, α,β-unsaturated carbonyl compounds via the Meyer–Schuster rearrangement and others. It can be oxidized to propynal or propargylic acid. As an indication of the electronegativity of an Orbital hybri ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Structural Formula Of Propargyl Alcohol
A structure is an arrangement and organization of interrelated elements in a material object or system, or the object or system so organized. Material structures include man-made objects such as buildings and machines and natural objects such as biological organisms, minerals and chemicals. Abstract structures include data structures in computer science and musical form. Types of structure include a hierarchy (a cascade of one-to-many relationships), a network featuring many-to-many links, or a lattice featuring connections between components that are neighbors in space. Load-bearing Buildings, aircraft, skeletons, anthills, beaver dams, bridges and salt domes are all examples of load-bearing structures. The results of construction are divided into buildings and non-building structures, and make up the infrastructure of a human society. Built structures are broadly divided by their varying design approaches and standards, into categories including building structure ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alkynes
\ce \ce Acetylene \ce \ce \ce Propyne \ce \ce \ce \ce 1-Butyne In organic chemistry, an alkyne is an unsaturated hydrocarbon containing at least one carbon—carbon triple bond. The simplest acyclic alkynes with only one triple bond and no other functional groups form a homologous series with the general chemical formula . Alkynes are traditionally known as acetylenes, although the name ''acetylene'' also refers specifically to , known formally as ethyne using IUPAC nomenclature. Like other hydrocarbons, alkynes are generally hydrophobic. Structure and bonding In acetylene, the H–C≡C bond angles are 180°. By virtue of this bond angle, alkynes are rod-like. Correspondingly, cyclic alkynes are rare. Benzyne cannot be isolated. The C≡C bond distance of 121 picometers is much shorter than the C=C distance in alkenes (134 pm) or the C–C bond in alkanes (153 pm). : The triple bond is very strong with a bond strength of 839 kJ/mol. The sigma bond contributes ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alcohols
In chemistry, an alcohol is a type of organic compound that carries at least one hydroxyl () functional group bound to a saturated carbon atom. The term ''alcohol'' originally referred to the primary alcohol ethanol (ethyl alcohol), which is used as a drug and is the main alcohol present in alcoholic drinks. An important class of alcohols, of which methanol and ethanol are the simplest examples, includes all compounds which conform to the general formula . Simple monoalcohols that are the subject of this article include primary (), secondary () and tertiary () alcohols. The suffix ''-ol'' appears in the IUPAC chemical name of all substances where the hydroxyl group is the functional group with the highest priority. When a higher priority group is present in the compound, the prefix ''hydroxy-'' is used in its IUPAC name. The suffix ''-ol'' in non-IUPAC names (such as paracetamol or cholesterol) also typically indicates that the substance is an alcohol. However, some compound ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydroxy Group
In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry, alcohols and carboxylic acids contain one or more hydroxy groups. Both the negatively charged anion , called hydroxide, and the neutral radical , known as the hydroxyl radical, consist of an unbonded hydroxy group. According to IUPAC definitions, the term ''hydroxyl'' refers to the hydroxyl radical () only, while the functional group is called a ''hydroxy group''. Properties Water, alcohols, carboxylic acids, and many other hydroxy-containing compounds can be readily deprotonated due to a large difference between the electronegativity of oxygen (3.5) and that of hydrogen (2.1). Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack this ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alkynylation
In organic chemistry, alkynylation is an addition reaction in which a terminal alkyne () is added to a carbonyl group () to form an Alpha and beta carbon, α-alkynyl alcohol (chemistry), alcohol (). When the acetylide is formed from acetylene (), the reaction gives an α-ethynyl alcohol. This process is often referred to as ethynylation. Such processes often involve metal acetylide intermediates. Scope The principal reaction of interest involves the addition of the acetylene () to a ketone () or aldehyde (): :RR'C=O + HC#CR'' -> RR'C(OH)C#CR'' The reaction proceeds with retention of the triple bond. For aldehydes and unsymmetrical ketones, the product is chiral, hence there is interest in asymmetric variants. These reactions invariably involve metal-acetylide intermediates. This reaction was discovered by chemist John Ulric Nef (chemist), John Ulric Nef in 1899 while experimenting with reactions of elemental sodium, phenylacetylene, and acetophenone. For this reason, the re ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Norman L
Norman or Normans may refer to: Ethnic and cultural identity * The Normans, a people partly descended from Norse Vikings who settled in the territory of Normandy in France in the 10th and 11th centuries ** People or things connected with the Norman conquest of southern Italy in the 11th and 12th centuries ** Norman dynasty, a series of monarchs in England and Normandy ** Norman architecture, romanesque architecture in England and elsewhere ** Norman language, spoken in Normandy ** People or things connected with the French region of Normandy Arts and entertainment * ''Norman'' (film), a 2010 drama film * '' Norman: The Moderate Rise and Tragic Fall of a New York Fixer'', a 2016 film * ''Norman'' (TV series), a 1970 British sitcom starring Norman Wisdom * ''The Normans'' (TV series), a documentary * "Norman" (song), a 1962 song written by John D. Loudermilk and recorded by Sue Thompson * "Norman (He's a Rebel)", a song by Mo-dettes from ''The Story So Far'', 1980 Businesses * ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Michael P
Michael may refer to: People * Michael (given name), a given name * Michael (surname), including a list of people with the surname Michael Given name "Michael" * Michael (archangel), ''first'' of God's archangels in the Jewish, Christian and Islamic religions * Michael (bishop elect), English 13th-century Bishop of Hereford elect * Michael (Khoroshy) (1885–1977), cleric of the Ukrainian Orthodox Church of Canada * Michael Donnellan (1915–1985), Irish-born London fashion designer, often referred to simply as "Michael" * Michael (footballer, born 1982), Brazilian footballer * Michael (footballer, born 1983), Brazilian footballer * Michael (footballer, born 1993), Brazilian footballer * Michael (footballer, born February 1996), Brazilian footballer * Michael (footballer, born March 1996), Brazilian footballer * Michael (footballer, born 1999), Brazilian footballer Rulers =Byzantine emperors= *Michael I Rangabe (d. 844), married the daughter of Emperor Nikephoros I * M ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Don C
Don Crawley, known professionally as Don C, is an American streetwear designer from Chicago, Illinois. His family comes from Louisiana. Crawley was a manager for Kanye West, and an executive at Kanye West's G.O.O.D. Music label. He was also the best man at the wedding of Kanye West and Kim Kardashian. Don C has gotten a shoutout in multiple of Kanye's songs: “Erase Me” (Kid Cudi), “Keep My Spirit Alive”, "I Am A God" and “Facts”. After getting in trouble with the paparazzi, Don C was eventually set on fashion. In 2011, he founded of the street-wear and sports apparel brand Just Don. He also owns a luxury clothing store chain, RSVP Gallery with Virgil Abloh. Personal life He is of Louisiana Creole descent. Collaborations Don C first collaborated with Jordan in January 2015, redesigning the Jordan 2 with a blue quilted design. This design took off and gave both Nike and Don C much attention. For one of Don C's most recent collaborations, in May 2017, he created ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carl R
Carl may refer to: *Carl, Georgia, city in USA *Carl, West Virginia, an unincorporated community * Carl (name), includes info about the name, variations of the name, and a list of people with the name *Carl², a TV series * "Carl", an episode of television series ''Aqua Teen Hunger Force'' * An informal nickname for a student or alum of Carleton College CARL may refer to: *Canadian Association of Research Libraries *Colorado Alliance of Research Libraries See also * Carle (other) * Charles *Carle, a surname *Karl (other) *Karle (other) Karle may refer to: Places * Karle (Svitavy District), a municipality and village in the Czech Republic * Karli, India, a town in Maharashtra, India ** Karla Caves, a complex of Buddhist cave shrines * Karle, Belgaum, a settlement in Belgaum ... {{disambig ja:カール zh:卡尔 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Norman A
Norman or Normans may refer to: Ethnic and cultural identity * The Normans, a people partly descended from Norse Vikings who settled in the territory of Normandy in France in the 10th and 11th centuries ** People or things connected with the Norman conquest of southern Italy in the 11th and 12th centuries ** Norman dynasty, a series of monarchs in England and Normandy ** Norman architecture, romanesque architecture in England and elsewhere ** Norman language, spoken in Normandy ** People or things connected with the French region of Normandy Arts and entertainment * ''Norman'' (film), a 2010 drama film * '' Norman: The Moderate Rise and Tragic Fall of a New York Fixer'', a 2016 film * ''Norman'' (TV series), a 1970 British sitcom starring Norman Wisdom * ''The Normans'' (TV series), a documentary * "Norman" (song), a 1962 song written by John D. Loudermilk and recorded by Sue Thompson * "Norman (He's a Rebel)", a song by Mo-dettes from ''The Story So Far'', 1980 Businesses * ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
