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Attosecond Chronoscopy
Attosecond chronoscopy are measurement techniques for attosecond-scale delays of atomic and molecular single photon processes like photoemission /en.wikipedia.org/wiki/Attosecond_chronoscopy#endnote_delayand photoionization. Ionization-delay measurements in atomic targets provide a wealth of information about the timing of the photoelectric effect, resonances, electron correlations and transport. Attosecond chronoscopy deals with the time resolved observation of ultrafast electronic processes of quantum physics of matter with applications to atoms, molecules and solids. Typical time scales covered range from attoseconds (10−18 sec.) to femtoseconds (10−15 sec.). Realtime observations of such processes has become possible since the turn of the millennium when well-controlled subfemtosecond laser pulses became available. Chronoscopy can provide information complementary to that accessible through conventional spectroscopy. While spectroscopy aims at characterizing processes thr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Attosecond
An attosecond (symbol as) is a unit of time in the International System of Units (SI) equal to 1×10−18 of a second (one quintillionth of a second). For comparison, an attosecond is to a second what a second is to about 31.71 billion years.Electron Motion Filmed 28 February 2008 The word "attosecond" is formed by the ''atto'' and the ''second''. ''Atto-'' was derived from the Danish word for eighteen (''atten''). Its symbol is as. An attosecond is equal ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photoemission
The photoelectric effect is the emission of electrons when electromagnetic radiation, such as light, hits a material. Electrons emitted in this manner are called photoelectrons. The phenomenon is studied in condensed matter physics, and solid state and quantum chemistry to draw inferences about the properties of atoms, molecules and solids. The effect has found use in electronic devices specialized for light detection and precisely timed electron emission. The experimental results disagree with classical electromagnetism, which predicts that continuous light waves transfer energy to electrons, which would then be emitted when they accumulate enough energy. An alteration in the intensity of light would theoretically change the kinetic energy of the emitted electrons, with sufficiently dim light resulting in a delayed emission. The experimental results instead show that electrons are dislodged only when the light exceeds a certain frequency—regardless of the light's intensity or d ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photoionization
Photoionization is the physical process in which an ion is formed from the interaction of a photon with an atom or molecule. Cross section Not every interaction between a photon and an atom, or molecule, will result in photoionization. The probability of photoionization is related to the photoionization cross section of the species -- the probability of an ionization event conceptualized as a hypothetical cross-sectional area. This cross section depends on the energy of the photon (proportional to its wavenumber) and the species being considered i.e. it depends on the structure of the molecular species. In the case of molecules, the photoionization cross-section can be estimated by examination of Franck-Condon factors between a ground-state molecule and the target ion. This can be initialized by computing the vibrations of a molecule and associated cation (post ionization) using quantum chemical software e.g. QChem. For photon energies below the ionization threshold, the photoion ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Arrow Of Time
The arrow of time, also called time's arrow, is the concept positing the "one-way direction" or " asymmetry" of time. It was developed in 1927 by the British astrophysicist Arthur Eddington, and is an unsolved general physics question. This direction, according to Eddington, could be determined by studying the organization of atoms, molecules, and bodies, and might be drawn upon a four-dimensional relativistic map of the world ("a solid block of paper"). Physical processes at the microscopic level are believed to be either entirely or mostly time-symmetric: if the direction of time were to reverse, the theoretical statements that describe them would remain true. Yet at the macroscopic level it often appears that this is not the case: there is an obvious direction (or ''flow'') of time. Overview The symmetry of time (T-symmetry) can be understood simply as the following: if time were perfectly symmetrical, a video of real events would seem realistic whether played forward ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Attophysics
Attosecond physics, also known as attophysics, or more generally attosecond science, is a branch of physics that deals with light-matter interaction phenomena wherein attosecond (10−18 s) photon pulses are used to unravel dynamical processes in matter with unprecedented time resolution. Attosecond science mainly employs pump–probe spectroscopic methods to investigate the physical process of interest. Due to the complexity of this field of study, it generally requires a synergistic interplay between state-of-the-art experimental setup and advanced theoretical tools to interpret the data collected from attosecond experiments. The main interests of attosecond physics are: # Atomic physics: investigation of electron correlation effects, photo-emission delay and ionization tunneling. # Molecular physics and molecular chemistry: role of electronic motion in molecular excited states (e.g. charge-transfer processes), light-induced photo-fragmentation, and light-induced electron t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Time-resolved Spectroscopy
In physics and physical chemistry, time-resolved spectroscopy is the study of dynamic processes in materials or chemical compounds by means of spectroscopic techniques. Most often, processes are studied after the illumination of a material occurs, but in principle, the technique can be applied to any process that leads to a change in properties of a material. With the help of pulsed lasers, it is possible to study processes that occur on time scales as short as 10−16 seconds. All time-resolved spectra are suitable to be analyzed using the two-dimensional correlation method for a correlation map between the peaks. Transient-absorption spectroscopy Transient-absorption spectroscopy (TAS), also known as flash photolysis, is an extension of absorption spectroscopy. Ultrafast transient absorption spectroscopy, an example of non-linear spectroscopy, measures changes in the absorbance/transmittance in the sample. Here, the absorbance at a particular wavelength or range of wavelengths ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atomic Physics
Atomic physics is the field of physics that studies atoms as an isolated system of electrons and an atomic nucleus. Atomic physics typically refers to the study of atomic structure and the interaction between atoms. It is primarily concerned with the way in which electrons are arranged around the nucleus and the processes by which these arrangements change. This comprises ions, neutral atoms and, unless otherwise stated, it can be assumed that the term ''atom'' includes ions. The term ''atomic physics'' can be associated with nuclear power and nuclear weapons, due to the synonymous use of ''atomic'' and ''nuclear'' in standard English. Physicists distinguish between atomic physics—which deals with the atom as a system consisting of a nucleus and electrons—and nuclear physics, which studies nuclear reactions and special properties of atomic nuclei. As with many scientific fields, strict delineation can be highly contrived and atomic physics is often considered in the wider c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
