Adiabatic Theorem
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Adiabatic Theorem
The adiabatic theorem is a concept in quantum mechanics. Its original form, due to Max Born and Vladimir Fock (1928), was stated as follows: :''A physical system remains in its instantaneous eigenstate if a given perturbation is acting on it slowly enough and if there is a gap between the eigenvalue and the rest of the Hamiltonian's spectrum.'' In simpler terms, a quantum mechanical system subjected to gradually changing external conditions adapts its functional form, but when subjected to rapidly varying conditions there is insufficient time for the functional form to adapt, so the spatial probability density remains unchanged. Diabatic vs. adiabatic processes At some initial time t_0 a quantum-mechanical system has an energy given by the Hamiltonian \hat(t_0); the system is in an eigenstate of \hat(t_0) labelled \psi(x,t_0). Changing conditions modify the Hamiltonian in a continuous manner, resulting in a final Hamiltonian \hat(t_1) at some later time t_1. The system will e ...
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Quantum Mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, quantum field theory, quantum technology, and quantum information science. Classical physics, the collection of theories that existed before the advent of quantum mechanics, describes many aspects of nature at an ordinary (macroscopic) scale, but is not sufficient for describing them at small (atomic and subatomic) scales. Most theories in classical physics can be derived from quantum mechanics as an approximation valid at large (macroscopic) scale. Quantum mechanics differs from classical physics in that energy, momentum, angular momentum, and other quantities of a bound system are restricted to discrete values ( quantization); objects have characteristics of both particles and waves (wave–particle duality); and there are limits to ...
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Old Quantum Theory
The old quantum theory is a collection of results from the years 1900–1925 which predate modern quantum mechanics. The theory was never complete or self-consistent, but was rather a set of heuristic corrections to classical mechanics. The theory is now understood as the semi-classical approximation to modern quantum mechanics. The main and final accomplishments of the old quantum theory were the determination of the modern form of the periodic table by Edmund Stoner and the Pauli Exclusion Principle which were both premised on the Arnold Sommerfeld enhancements to the Bohr model of the atom. The main tool of the old quantum theory was the Bohr–Sommerfeld quantization condition, a procedure for selecting out certain states of a classical system as allowed states: the system can then only exist in one of the allowed states and not in any other state. History The old quantum theory was instigated by the 1900 work of Max Planck on the emission and absorption of light in a bla ...
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Bra–ket Notation
In quantum mechanics, bra–ket notation, or Dirac notation, is used ubiquitously to denote quantum states. The notation uses angle brackets, and , and a vertical bar , to construct "bras" and "kets". A ket is of the form , v \rangle. Mathematically it denotes a vector, \boldsymbol v, in an abstract (complex) vector space V, and physically it represents a state of some quantum system. A bra is of the form \langle f, . Mathematically it denotes a linear form f:V \to \Complex, i.e. a linear map that maps each vector in V to a number in the complex plane \Complex. Letting the linear functional \langle f, act on a vector , v\rangle is written as \langle f , v\rangle \in \Complex. Assume that on V there exists an inner product (\cdot,\cdot) with antilinear first argument, which makes V an inner product space. Then with this inner product each vector \boldsymbol \phi \equiv , \phi\rangle can be identified with a corresponding linear form, by placing the vector in the anti-line ...
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Magnetic Field
A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to the magnetic field. A permanent magnet's magnetic field pulls on ferromagnetic materials such as iron, and attracts or repels other magnets. In addition, a nonuniform magnetic field exerts minuscule forces on "nonmagnetic" materials by three other magnetic effects: paramagnetism, diamagnetism, and antiferromagnetism, although these forces are usually so small they can only be detected by laboratory equipment. Magnetic fields surround magnetized materials, and are created by electric currents such as those used in electromagnets, and by electric fields varying in time. Since both strength and direction of a magnetic field may vary with location, it is described mathematically by a function assigning a vector to each point of space, cal ...
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Energy Level
A quantum mechanical system or particle that is bound—that is, confined spatially—can only take on certain discrete values of energy, called energy levels. This contrasts with classical particles, which can have any amount of energy. The term is commonly used for the energy levels of the electrons in atoms, ions, or molecules, which are bound by the electric field of the nucleus, but can also refer to energy levels of nuclei or vibrational or rotational energy levels in molecules. The energy spectrum of a system with such discrete energy levels is said to be quantized. In chemistry and atomic physics, an electron shell, or principal energy level, may be thought of as the orbit of one or more electrons around an atom's nucleus. The closest shell to the nucleus is called the " shell" (also called "K shell"), followed by the " shell" (or "L shell"), then the " shell" (or "M shell"), and so on farther and farther from the nucleus. The shells correspond with the principal quan ...
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Linear Superposition
The superposition principle, also known as superposition property, states that, for all linear systems, the net response caused by two or more stimuli is the sum of the responses that would have been caused by each stimulus individually. So that if input ''A'' produces response ''X'' and input ''B'' produces response ''Y'' then input (''A'' + ''B'') produces response (''X'' + ''Y''). A function F(x) that satisfies the superposition principle is called a linear function. Superposition can be defined by two simpler properties: additivity F(x_1+x_2)=F(x_1)+F(x_2) \, and homogeneity F(a x)=a F(x) \, for scalar . This principle has many applications in physics and engineering because many physical systems can be modeled as linear systems. For example, a beam can be modeled as a linear system where the input stimulus is the load on the beam and the output response is the deflection of the beam. The importance of linear systems is that they are easier to analyze mathematically; the ...
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Quantum Number
In quantum physics and chemistry, quantum numbers describe values of conserved quantities in the dynamics of a quantum system. Quantum numbers correspond to eigenvalues of operators that commute with the Hamiltonian—quantities that can be known with precision at the same time as the system's energyspecifically, observables \widehat that commute with the Hamiltonian are simultaneously diagonalizable with it and so the eigenvalues a and the energy (eigenvalues of the Hamiltonian) are not limited by an uncertainty relation arising from non-commutativity.—and their corresponding eigenspaces. Together, a specification of all of the quantum numbers of a quantum system fully characterize a basis state of the system, and can in principle be measured together. An important aspect of quantum mechanics is the quantization of many observable quantities of interest.Many observables have discrete spectra (sets of eigenvalues) in quantum mechanics, so the quantities can only be measure ...
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Potential Energy
In physics, potential energy is the energy held by an object because of its position relative to other objects, stresses within itself, its electric charge, or other factors. Common types of potential energy include the gravitational potential energy of an object, the elastic potential energy of an extended spring, and the electric potential energy of an electric charge in an electric field. The unit for energy in the International System of Units (SI) is the joule, which has the symbol J. The term ''potential energy'' was introduced by the 19th-century Scottish engineer and physicist William Rankine, although it has links to Greek philosopher Aristotle's concept of potentiality. Potential energy is associated with forces that act on a body in a way that the total work done by these forces on the body depends only on the initial and final positions of the body in space. These forces, that are called ''conservative forces'', can be represented at every point in space by vec ...
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Spring Constant
In physics, Hooke's law is an empirical law which states that the force () needed to extend or compress a spring (device), spring by some distance () Proportionality (mathematics)#Direct_proportionality, scales linearly with respect to that distance—that is, where is a constant factor characteristic of the spring (i.e., its stiffness), and is small compared to the total possible deformation of the spring. The law is named after 17th-century British physicist Robert Hooke. He first stated the law in 1676 as a Latin anagram. He published the solution of his anagram in 1678 as: ("as the extension, so the force" or "the extension is proportional to the force"). Hooke states in the 1678 work that he was aware of the law since 1660. Hooke's equation holds (to some extent) in many other situations where an elasticity (physics), elastic body is Deformation (physics), deformed, such as wind blowing on a tall building, and a musician plucking a string (music), string of a guitar ...
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Quantum Harmonic Oscillator
量子調和振動子 は、 古典調和振動子 の 量子力学 類似物です。任意の滑らかな ポテンシャル は通常、安定した 平衡点 の近くで 調和ポテンシャル として近似できるため、最も量子力学における重要なモデル系。さらに、これは正確な 解析解法が知られている数少ない量子力学系の1つである。 author=Griffiths, David J. , title=量子力学入門 , エディション=2nd , 出版社=プレンティス・ホール , 年=2004 , isbn=978-0-13-805326-0 , author-link=David Griffiths (物理学者) , URL アクセス = 登録 , url=https://archive.org/details/introductiontoel00grif_0 One-dimensional harmonic oscillator Hamiltonian and energy eigenstates 粒子の ハミルトニアン は次のとおりです。 \hat H = \frac + \frac k ^2 = \frac + \frac m \omega^2 ^2 \, , ここで、 は粒子の質量、 は力定数、\omega = \sqrt は 動子の [角周波数 ...
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Classical Physics
Classical physics is a group of physics theories that predate modern, more complete, or more widely applicable theories. If a currently accepted theory is considered to be modern, and its introduction represented a major paradigm shift, then the previous theories, or new theories based on the older paradigm, will often be referred to as belonging to the area of "classical physics". As such, the definition of a classical theory depends on context. Classical physical concepts are often used when modern theories are unnecessarily complex for a particular situation. Most often ''classical physics'' refers to pre-1900 physics, while ''modern physics'' refers to post-1900 physics which incorporates elements of quantum mechanics and theory of relativity, relativity. Overview Classical theory has at least two distinct meanings in physics. In the context of quantum mechanics, classical theory refers to theory, theories of physics that do not use the Quantization (physics), quantisation ...
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