4,4'-Methylenedianiline
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4,4'-Methylenedianiline
4,4′-Methylenedianiline (MDA) is an organic compound with the formula CH2(C6H4NH2)2. It is a colorless solid, although commercial samples can appear yellow or brown. It is produced on an industrial scale, mainly as a precursor to polyurethanes. Synthesis and applications In the industrial production, MDA is produced by reaction of formaldehyde and aniline in the presence of hydrochloric acid. MDA is consumed mainly as a precursor to Methylene diphenyl diisocyanate (MDI). MDA is treated with phosgene to produce MDI. MDI is a precursor to many polyurethane foams. Lower quantities are used as hardeners in epoxy resins and adhesives, as well as in the production of high-performance polymers. Additionally, hydrogenation of MDA can be performed to produce 4,4,diaminodicyclohexylmethane, which is also used in polymer chemistry. Safety MDA is considered a potential occupational carcinogen by the US National Institute for Occupational Safety and Health. The Occupational Safety a ...
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4,4'-Oxydianiline
4,4′-Oxydianiline (ODA) is an organic compound with the formula O( C6 H4 NH2)2. It is an ether derivative of aniline. This colourless solid is a useful monomer and cross-linking agent for polymers, especially the polyimides, such as Kapton. Uses 4,4′-Oxydianiline is used in the production of a wide variety of polymer resins. The primary use lies in the production of polyimide and poly(ester)imide resins. These resins are used for their temperature-resistant properties and are utilized in products including wire enamels, coatings, film, adhesives, insulating varnishes, coated fabrics, flame-retardant fibers, oil sealants and retainers, insulation for cables and printed circuits, and laminates and composite for aerospace vehicles. Other applications of 4,4′-oxydianiline include the production of poly(amide)imide resins (which are used in the manufacture of heat-resistant wire enamels and coatings), as an intermediate in the manufacture of epoxy resins and adhesives, and in ...
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