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2,3,3-trimethylpentane
2,3,3-Trimethylpentane is a chemical compound in the family of hydrocarbons which has a formula of C8H18. It is an isomer of octane. It has a role as a human metabolite, a bacterial metabolite and a mammalian metabolite. It is an alkane and a volatile organic compound Some chemical authorities define an organic compound as a chemical compound that contains a carbon–hydrogen or carbon–carbon bond; others consider an organic compound to be any chemical compound that contains carbon. For example, carbon-co .... References Alkanes {{Hydrocarbon-stub ...
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Alkane
In organic chemistry, an alkane, or paraffin (a historical trivial name that also has other meanings), is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in which all the carbon–carbon bonds are single. Alkanes have the general chemical formula . The alkanes range in complexity from the simplest case of methane (), where ''n'' = 1 (sometimes called the parent molecule), to arbitrarily large and complex molecules, like hexacontane () or 4-methyl-5-(1-methylethyl) octane, an isomer of dodecane (). The International Union of Pure and Applied Chemistry (IUPAC) defines alkanes as "acyclic branched or unbranched hydrocarbons having the general formula , and therefore consisting entirely of hydrogen atoms and saturated carbon atoms". However, some sources use the term to denote ''any'' saturated hydrocarbon, including those that are either monocyclic (i.e. the cycloalkanes) or polycycl ...
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2,2-Dimethylbutane
2,2-Dimethylbutane, trivially known as neohexane at William Odling's 1876 suggestion, is an organic compound with formula C6H14 or (H3C-)3-C-CH2-CH3. It is therefore an alkane, indeed the most compact and branched of the hexane isomers — the only one with a quaternary carbon and a butane (C4) backbone. Synthesis Butlerov's student V. Goryainov originally discovered neohexane in 1872 by cross-coupling of zinc ethyl with tert-butyl iodide. 2,2-Dimethylbutane can be synthesised by the hydroisomerisation of 2,3-dimethylbutane using an acid catalyst. It can also be synthesised by isomerization of ''n''-pentane in the presence of a catalyst containing combinations of one or more of palladium, platinum, rhodium and rhenium on a matrix of zeolite, alumina, silicon dioxide or other materials. Such reactions create a mixture of final products including isopentane, ''n''-hexane, 3-methylpentane, 2-methylpentane, 2,3-dimethylbutane and 2,2-dimethylbutane. Since the composition of ...
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2,3-Dimethylbutane
2,3-Dimethylbutane is an isomer of hexane. It has the chemical formula A chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as pare ... (CH3)2CHCH(CH3)2. It is a colorless liquid which boils at 57.9 °C. References Alkanes {{Hydrocarbon-stub ...
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Triptane
Triptane, or 2,2,3-trimethylbutane, is an organic chemical compound with the molecular formula C7 H16 or (H3C-)3C-C(-CH3)2H. It is therefore an alkane, specifically the most compact and heavily branched of the heptane isomers, the only one with a butane (C4) backbone. It was first synthesized in 1922 by Belgian chemists Georges Chavanne (1875–1941) and B. Lejeune, who called it trimethylisopropylmethane. Due to its high octane rating (112–113 RON, 101 MON) triptane was produced on alkylation units starting from 1943 for use as an anti-knock additive in gasoline. It was extensively researched for this role and received the modern name in the late 1930s at a joint laboratory of NACA, National Bureau of Standards, US Army Air Corps and the Bureau of Aeronautics. As of 2011, it was not a significant component of US automobile gasoline, present only in trace amounts (0.05–0.1%). See also *List of gasoline additives Gasoline additives may increase gasoline's octane rating ...
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Tetramethylbutane
Tetramethylbutane, sometimes called hexamethylethane, is a hydrocarbon with formula C8H18 or (H3C-)3C-C(-CH3)3. It is the most heavily branched and most compact of the octane isomers, the only one with a butane (C4) backbone. Because of its highly symmetrical structure, it has a very high melting point and a short liquid range; in fact, it is the smallest saturated acyclic hydrocarbon that appears as a solid at a room temperature of 25 °C. (Among cyclic hydrocarbons, cubane, C8H8, norbornane, C7H12 and norbornene, C7H10 are even smaller and are also solid at room temperature.) It is also the most stable C8H18 isomer, with a heat of formation lower than that of ''n''-octane, a fact that has been attributed to stabilizing dispersive interactions (electron correlation) between the methyl groups (protobranching). The compound can be obtained from ethyl bromide, ''tert''-butyl bromide, and magnesium metal in the presence of manganese( II) ions. Despite conditions amenable to t ...
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Tetraethylmethane
Tetraethylmethane is a branched alkane with 9 carbon atoms. It is a colorless, highly flammable, and volatile liquid at room temperature. It is one of the isomers of nonane. References See also *Neopentane Neopentane, also called 2,2-dimethylpropane, is a double-branched-chain alkane with five carbon atoms. Neopentane is a flammable gas at room temperature and pressure which can condense into a highly volatile liquid on a cold day, in an ice bat ... * Tetraethynylmethane * Tetramethoxymethane External links * {{cite journal , doi = 10.1021/jo981779m , title = Molecular Structure of 3,3-Diethylpentane (Tetraethylmethane) in the Gas Phase as Determined by Electron Diffraction and ab Initio Calculations , journal = The Journal of Organic Chemistry , volume = 64 , issue = 12 , pages = 4226–4232 , year = 1999 , last1 = Alder , first1 = Roger W. , last2 = Allen , first2 = Paul R. , last3 = Hnyk , first3 = Drahomír , last4 = Rankin , first4 = David W. H. , ...
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2,2,4-Trimethylpentane
2,2,4-Trimethylpentane, also known as isooctane or iso-octane, is an organic compound with the formula (CH3)3CCH2CH(CH3)2. It is one of several isomers of octane (C8H18). This particular isomer is the standard 100 point on the octane rating scale (the zero point is ''n''-heptane). It is an important component of gasoline, frequently used in relatively large proportions (around 10%) to increase the knock resistance of fuel. Strictly speaking, if the standard meaning of ‘iso’ is followed, the name ''isooctane'' should be reserved for the isomer 2-methylheptane. However, 2,2,4-trimethylpentane is by far the most important isomer of octane and historically it has been assigned this name. Production Isooctane is produced on a massive scale in the petroleum industry by alkylation of isobutene with isobutane. This process is conducted in alkylation units in the presence of acid catalysts. : It can also be produced from isobutylene by dimerization using an Amberlyst cataly ...
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2,3,4-Trimethylpentane
2,3,4-Trimethylpentane is a branched alkane. It is one of the isomers of octane Octane is a hydrocarbon and also an alkane with the chemical formula C8H18, and the condensed structural formula CH3(CH2)6CH3. Octane has many structural isomers that differ by the location of branching in the carbon chain. One of these isomers .... References External links2,3,4-Trimethylpentaneat environmentalchemistry.com Alkanes {{Hydrocarbon-stub ...
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Tetra-tert-butylmethane
Tetra-''tert''-butylmethane is a hypothetical organic compound with formula C17H36, consisting of four ''tert''-butyl groups bonded to a central carbon atom. It would be an alkane, specifically the most compact branched isomer of heptadecane. Some calculations suggest this compound cannot exist due to the steric hindrance among the closely packed ''tert''-butyl groups, which would make it one of the smallest, if not the smallest itself, saturated and acyclic hydrocarbon that cannot exist. Other calculations suggest that the molecule would be stable, with the C–C bonds to the central ("methane") carbon having a length of 166.1 pm — longer than the typical C−C bond in order to reduce steric effects, but still shorter than those found in some other real molecules. See also * Neopentane * Tetrakis(trimethylsilyl)methane * Tetrafluoromethane * Tetrachloromethane * Tetrabromomethane * Tetraiodomethane * Tetraazidomethane * Tetracyanomethane * Tetraethynylmethane * Tetranitr ...
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2,3-Dimethylhexane
2,3-Dimethylhexane is a structural isomer of octane Octane is a hydrocarbon and also an alkane with the chemical formula C8H18, and the condensed structural formula CH3(CH2)6CH3. Octane has many structural isomers that differ by the location of branching in the carbon chain. One of these isomers .... References {{DEFAULTSORT:Dimethylhexane, 2,3- Alkanes Hydrocarbons ...
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2,5-Dimethylhexane
2,5-Dimethylhexane is a branched alkane used in the aviation industry in low revolutions per minute helicopters. As an isomer of octane, the boiling point The boiling point of a substance is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid and the liquid changes into a vapor. The boiling point of a liquid varies depending upon the surrounding envi ... is very close to that of octane, but can in pure form be slightly lower. 2,5-Dimethylhexane is moderately toxic. References {{DEFAULTSORT:Dimethylhexane, 2,5- Alkanes ...
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Hydrocarbon
In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and Hydrophobe, hydrophobic; their odor is usually faint, and may be similar to that of gasoline or Naphtha, lighter fluid. They occur in a diverse range of molecular structures and phases: they can be gases (such as methane and propane), liquids (such as hexane and benzene), low melting solids (such as paraffin wax and naphthalene) or polymers (such as polyethylene and polystyrene). In the fossil fuel industries, ''hydrocarbon'' refers to naturally occurring petroleum, natural gas and coal, or their hydrocarbon derivatives and purified forms. Combustion of hydrocarbons is the main source of the world's energy. Petroleum is the dominant raw-material source for organic commodity chemicals such as solvents and polymers. Most anthropogenic (human-generated) emissions of greenhouse gases are eithe ...
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