2,4,5-Trimethoxypropiophenone
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2,4,5-Trimethoxypropiophenone
2,4,5-Trimethoxypropiophenone is a natural phenylpropanoid and precursor in the synthesis of α-asarone. Natural occurrence 2,4,5-Trimethoxypropiophenone is a component of several plant species' essential oils. The chemical has been identified in ''Piper marginatum ''Piper marginatum'', the cake bush, Anesi wiwiri, marigold pepper, Ti Bombé in Creole or Hinojo, is a plant species in the genus ''Piper (plant), Piper'' found in moist, shady spots in the Amazon rainforest in Surinam, French Guiana and Brazil. ...'', '' Acorus tatarinowii'', and '' Asarum maximum''. References O-methylated phenylpropanoids Aromatic ketones {{organic-compound-stub ...
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Piper Marginatum
''Piper marginatum'', the cake bush, Anesi wiwiri, marigold pepper, Ti Bombé in Creole or Hinojo, is a plant species in the genus '' Piper'' found in moist, shady spots in the Amazon rainforest in Surinam, French Guiana and Brazil. The leaves contain flavonoids such as vitexin and marginatoside (6 -O-β gentiobiosyl vitexin). The plant also contains 3,4-Methylenedioxypropiophenone, 2,4,5-Trimethoxypropiophenone, 2-Methoxy-4,5-methylenedioxypropiophenone, 1-(3,4-Methylenedioxyphenyl)propan-1-ol ( Marginatumol), 5,4′-Dihydroxy-7-methoxyflavanone and 5,7-Dihydroxy-4′-methoxyflavanone. An essential oil can be produced from the plant showing deterrent and larvicidal activities against ''Aedes aegypti ''Aedes aegypti'', the yellow fever mosquito, is a mosquito that can spread dengue fever, chikungunya, Zika fever, Mayaro and yellow fever viruses, and other disease agents. The mosquito can be recognized by black and white markings on its legs ...''. References Ext ...
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Asarone
Asarone is chemical compound of the phenylpropanoid class found in certain plants such as ''Acorus'' and ''Asarum''. There are two isomers, α (or ''trans'') and β (or ''cis''). As a volatile fragrance oil, it is used in killing pests and bacteria. Pharmacology The main clinical symptom of asarone is prolonged vomiting that sometimes lasted more than 15 hours. Asarone is not metabolized to trimethoxyamphetamine as has been claimed by online vendors. The Council of Europe Committee of Experts on Flavouring Substances concluded that β-asarone is clearly carcinogenic and has proposed limits for its concentration in flavorings such as bitters made from ''Acorus calamus'' (sweet flag). β-Asarone exhibits anti-fungal activity by inhibiting ergosterol biosynthesis in ''Aspergillus niger''. However, the toxicity and carcinogenicity of asarone means that it may be difficult to develop any practical medication based on it. See also * Elemicin Elemicin is a phenylpropene, a nat ...
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Phenylpropanoid
The phenylpropanoids are a diverse family of organic compounds that are synthesized by plants from the amino acids phenylalanine and tyrosine. Their name is derived from the six-carbon, aromatic phenyl group and the three-carbon propene tail of coumaric acid, which is the central intermediate in phenylpropanoid biosynthesis. From 4-coumaroyl-CoA emanates the biosynthesis of myriad natural products including lignols (precursors to lignin and lignocellulose), flavonoids, isoflavonoids, coumarins, aurones, stilbenes, catechin, and phenylpropanoids. The coumaroyl component is produced from cinnamic acid. Phenylpropanoids are found throughout the plant kingdom, where they serve as essential components of a number of structural polymers, provide protection from ultraviolet light, defend against herbivores and pathogens, and also mediate plant-pollinator interactions as floral pigments and scent compounds. Hydroxycinnamic acids Phenylalanine is first converted to cinnamic aci ...
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Precursor (chemistry)
In chemistry, a precursor is a compound that participates in a chemical reaction that produces another compound. In biochemistry, the term "precursor" often refers more specifically to a chemical compound preceding another in a metabolic pathway, such as a protein precursor. Illicit drug precursors In 1988, the United Nations Convention Against Illicit Traffic in Narcotic Drugs and Psychotropic Substances introduced detailed provisions and requirements relating the control of precursors used to produce drugs of abuse. In Europe the Regulation (EC) No. 273/2004 of the European Parliament and of the Council on drug precursors was adopted on 11 February 2004. ( European law on drug precursors) Illicit explosives precursors On January 15, 2013, the Regulation (EU) No. 98/2013 of the European Parliament and of the Council on the marketing and use of explosives precursors was adopted. The Regulation harmonises rules across Europe on the making available, introduction, possession and u ...
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Alpha And Beta Carbon
In the nomenclature of organic chemistry, a locant is a term to indicate the position of a functional group or substituent within a molecule. Numeric locants The International Union of Pure and Applied Chemistry (IUPAC) recommends the use of numeric prefixes to indicate the position of substituents, generally by identifying the parent hydrocarbon chain and assigning the carbon atoms based on their substituents in order of precedence. For example, there are at least two isomers of the linear form of pentanone, a ketone that contains a chain of exactly five carbon atoms. There is an oxygen atom bonded to one of the middle three carbons (if it were bonded to an end carbon, the molecule would be an aldehyde, not a ketone), but it is not clear where it is located. In this example, the carbon atoms are numbered from one to five, which starts at one end and proceeds sequentially along the chain. Now the position of the oxygen atom can be defined as on carbon atom number two, three or ...
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Essential Oil
An essential oil is a concentrated hydrophobic liquid containing volatile (easily evaporated at normal temperatures) chemical compounds from plants. Essential oils are also known as volatile oils, ethereal oils, aetheroleum, or simply as the oil of the plant from which they were extracted, such as oil of clove. An essential oil is essential in the sense that it contains the essence of the plant's fragrance—the characteristic fragrance of the plant from which it is derived. The term "essential" used here does ''not'' mean indispensable or usable by the human body, as with the terms essential amino acid or essential fatty acid, which are so called because they are nutritionally required by a living organism. Essential oils are generally extracted by distillation, often by using steam. Other processes include expression, solvent extraction, '' sfumatura'', absolute oil extraction, resin tapping, wax embedding, and cold pressing. They are used in perfumes, cosmetics, soaps, air ...
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Acorus Tatarinowii
''Acorus'' is a genus of monocot flowering plants. This genus was once placed within the family Araceae (aroids), but more recent classifications place it in its own family Acoraceae and order Acorales, of which it is the sole genus of the oldest surviving line of monocots. Some older studies indicated that it was placed in a lineage (the order Alismatales), that also includes aroids (Araceae), Tofieldiaceae, and several families of aquatic monocots (e.g., Alismataceae, Posidoniaceae). However, modern phylogenetic studies demonstrate that ''Acorus'' is sister to all other monocots. Common names include calamus and sweet flag. The genus is native to North America and northern and eastern Asia, and naturalised in southern Asia and Europe from ancient cultivation. The known wild populations are diploid except for some tetraploids in eastern Asia, while the cultivated plants are sterile triploids, probably of hybrid origin between the diploid and tetraploid forms. Characterist ...
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Asarum Maximum
''Asarum maximum'' is a species of plant in the family Aristolochiaceae. It is endemic to China. The flowers have a distinct smell of mushrooms. References maximum In mathematical analysis, the maxima and minima (the respective plurals of maximum and minimum) of a function, known collectively as extrema (the plural of extremum), are the largest and smallest value of the function, either within a given ran ... Flora of China Vulnerable plants Taxonomy articles created by Polbot {{Piperales-stub ...
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