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1912 In Science
The year 1912 in science and technology involved some significant events, listed below. Archaeology * December 6 – The Nefertiti Bust is found at Amarna in Egypt by the German Oriental Company (Deutsche Orient-Gesellschaft – DOG), led by German archaeologist Ludwig Borchardt. Astronomy * At the beginning of this year an extreme decadal variation in length of day produces mean solar days having a duration of 86400.00389 seconds of Terrestrial Time (or ephemeris time), the slowest rotation of Earth's crust ever to be recorded. Biology * July 23 – Horace Donisthorpe first discovers '' Anergates atratulus'' in the New Forest, England. * Reginald Punnett is appointed as first Arthur Balfour Professor of Genetics in the University of Cambridge (U.K.), probably the oldest chair of genetics in the English-speaking world. Chemistry * Peter Debye derives the T-cubed law for the low temperature heat capacity of a nonmetallic solid. * Casimir Funk introduces t ...
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Peter Debye
Peter Joseph William Debye ( ; born Petrus Josephus Wilhelmus Debije, ; March 24, 1884 – November 2, 1966) was a Dutch-American physicist and physical chemist, and Nobel laureate in Chemistry. Biography Early life Born in Maastricht, Netherlands, Debye enrolled in the Aachen University of Technology in 1901. In 1905, he completed his first degree in electrical engineering. He published his first paper, a mathematically elegant solution of a problem involving eddy currents, in 1907. At Aachen, he studied under the theoretical physicist Arnold Sommerfeld, who later claimed that his most important discovery was Peter Debye. In 1906, Sommerfeld received an appointment at Munich, Bavaria, and took Debye with him as his assistant. Debye got his Ph.D. with a dissertation on radiation pressure in 1908. In 1910, he derived the Planck radiation formula using a method which Max Planck agreed was simpler than his own. In 1911, when Albert Einstein took an appointment as a profes ...
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Acetylene
Acetylene (Chemical nomenclature, systematic name: ethyne) is a chemical compound with the formula and structure . It is a hydrocarbon and the simplest alkyne. This colorless gas is widely used as a fuel and a chemical building block. It is unstable in its pure form and thus is usually handled as a solution. Pure acetylene is odorless, but commercial grades usually have a marked odor due to impurities such as divinyl sulfide and phosphine.Compressed Gas Association (1995Material Safety and Data Sheet – Acetylene As an alkyne, acetylene is Saturated and unsaturated compounds, unsaturated because its two carbon atoms are Chemical bond, bonded together in a triple bond. The carbon–carbon triple bond places all four atoms in the same straight line, with CCH bond angles of 180°. The triple bond in acetylene results in a high energy content that is released when acetylene is burned. Discovery Acetylene was discovered in 1836 by Edmund Davy, who identified it as a "new carburet ...
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Acetic Acid
Acetic acid , systematically named ethanoic acid , is an acidic, colourless liquid and organic compound with the chemical formula (also written as , , or ). Vinegar is at least 4% acetic acid by volume, making acetic acid the main component of vinegar apart from water. Historically, vinegar was produced from the third century BC and was likely the first acid to be produced in large quantities. Acetic acid is the second simplest carboxylic acid (after formic acid). It is an important Reagent, chemical reagent and industrial chemical across various fields, used primarily in the production of cellulose acetate for photographic film, polyvinyl acetate for wood Adhesive, glue, and synthetic fibres and fabrics. In households, diluted acetic acid is often used in descaling agents. In the food industry, acetic acid is controlled by the E number, food additive code E260 as an acidity regulator and as a condiment. In biochemistry, the acetyl group, derived from acetic acid, is funda ...
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Vinyl Acetate
Vinyl acetate is an organic compound with the Chemical formula, formula CH3CO2CH=CH2. This colorless liquid is the precursor to polyvinyl acetate, ethylene-vinyl acetate copolymers, polyvinyl alcohol, and other important industrial polymers. Production The worldwide production capacity of vinyl acetate was estimated at 6,969,000 tonnes/year in 2007, with most capacity concentrated in the United States (1,585,000 all in Texas), China (1,261,000), Japan (725,000) and Taiwan (650,000). The average list price for 2008 was US$1600/tonne. Celanese is the largest producer (ca 25% of the worldwide capacity), while other significant producers include China Petrochemical Corporation (7%), Chang Chun Group (6%), and LyondellBasell (5%). Vinyl acetate is mainly (80%) polymerized, and the resulting polymer is hydrolyzed to give polyvinvyl alcohol. Preparation Vinyl acetate is the acetate ester of vinyl alcohol. Since vinyl alcohol is highly unstable (with respect to acetaldehyde), the prepara ...
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Patent
A patent is a type of intellectual property that gives its owner the legal right to exclude others from making, using, or selling an invention for a limited period of time in exchange for publishing an sufficiency of disclosure, enabling disclosure of the invention."A patent is not the grant of a right to make or use or sell. It does not, directly or indirectly, imply any such right. It grants only the right to exclude others. The supposition that a right to make is created by the patent grant is obviously inconsistent with the established distinctions between generic and specific patents, and with the well-known fact that a very considerable portion of the patents granted are in a field covered by a former relatively generic or basic patent, are tributary to such earlier patent, and cannot be practiced unless by license thereunder." – ''Herman v. Youngstown Car Mfg. Co.'', 191 F. 579, 584–85, 112 CCA 185 (6th Cir. 1911) In most countries, patent rights fall under private la ...
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Polyvinyl Acetate
Polyvinyl acetate (PVA, PVAc, poly(ethenyl ethanoate)), commonly known as wood glue (a term that may also refer to other types of glues), PVA glue, white glue, carpenter's glue, school glue, or Elmer's Glue in the US, is a widely available adhesive used for porous materials like wood, paper, and cloth. An aliphatic rubbery synthetic polymer with the formula (C4H6O2)''n'', it belongs to the polyvinyl ester family, with the general formula − COOCHCH2��. It is a type of thermoplastic. Properties The degree of polymerization of polyvinyl acetate is typically 100 to 5000, while its ester groups are sensitive to base hydrolysis and slowly convert PVAc into polyvinyl alcohol and acetic acid. The glass transition temperature of polyvinyl acetate is between 30 and 45 °C depending on the molecular weight. PVAc dispersions such as Elmer's Glue-All contain polyvinyl alcohol as a protective colloid. In alkaline conditions, boron compounds such as boric acid or borax cause the ...
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Fritz Klatte
Fritz Klatte (28 March 1880, Diepholz – 11 February 1934) was a German chemist and the discoverer of polyvinyl acetate, with German patent (GP 281687 1912) for its preparation from acetylene gas.See:(1) Deutsche Reichs Patent no. 281687 (4 July 1913), an abstract of which appears in the ''Journal of the Society of Chemical Industry (London)'', vol. 34, page 623 (1915);(2) Deutsche Reichs Patent no. 281688 (2 April 1914);(3) British patent no. 15271 (25 June 1914.); (4) Fritz Klatte and Adolf Rollett"Plastic composition and process of producing it," U.S. Patent 1,241,738 (filed: July 3, 1914; issued: Oct. 2, 1917), an abstract of which appears in the ''Journal of the Society of Chemical Industry (London)'', vol. 36, page 1185 (1917). Polyvinyl chloride (PVC) was discovered by French physicist A physicist is a scientist who specializes in the field of physics, which encompasses the interactions of matter and energy at all length and time scales in the physical universe. ...
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Canal Rays
An anode ray (also positive ray or canal ray) is a beam of positive ions that is created by certain types of gas-discharge tubes. They were first observed in Crookes tubes during experiments by the German scientist Eugen Goldstein, in 1886. Later work on anode rays by Wilhelm Wien and J. J. Thomson led to the development of mass spectrometry. Anode ray tube Goldstein used a gas-discharge tube which had a perforated cathode. When an electrical potential of several thousand volts is applied between the cathode and anode, faint luminous "rays" are seen extending from the holes in the back of the cathode. These rays are beams of particles moving in a direction opposite to the "cathode rays", which are streams of electrons which move toward the anode. Goldstein called these positive rays ''Kanalstrahlen'', "channel rays", or "canal rays", because these rays passed through the holes or ''channels'' in the cathode. The process by which anode rays are formed in a gas-discharge a ...
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Isotope
Isotopes are distinct nuclear species (or ''nuclides'') of the same chemical element. They have the same atomic number (number of protons in their Atomic nucleus, nuclei) and position in the periodic table (and hence belong to the same chemical element), but different nucleon numbers (mass numbers) due to different numbers of neutrons in their nuclei. While all isotopes of a given element have similar chemical properties, they have different atomic masses and physical properties. The term isotope is derived from the Greek roots isos (wikt:ἴσος, ἴσος "equal") and topos (wikt:τόπος, τόπος "place"), meaning "the same place"; thus, the meaning behind the name is that different isotopes of a single element occupy the same position on the periodic table. It was coined by Scottish doctor and writer Margaret Todd (doctor), Margaret Todd in a 1913 suggestion to the British chemist Frederick Soddy, who popularized the term. The number of protons within the atomic nuc ...
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Vitamin
Vitamins are Organic compound, organic molecules (or a set of closely related molecules called vitamer, vitamers) that are essential to an organism in small quantities for proper metabolism, metabolic function. Nutrient#Essential nutrients, Essential nutrients cannot be biosynthesis, synthesized in the organism in sufficient quantities for survival, and therefore must be obtained through the Diet (nutrition), diet. For example, vitamin C can be synthesized by some species but not by others; it is not considered a vitamin in the first instance but is in the second. Most vitamins are not single molecules, but groups of related molecules called vitamers. For example, there are eight vitamers of vitamin E: four tocopherols and four tocotrienols. The term ''vitamin'' does not include the three other groups of essential nutrients: mineral (nutrient), minerals, essential fatty acids, and essential amino acids. Major health organizations list thirteen vitamins: * Vitamin A (all-' ...
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Casimir Funk
Casimir Funk ( ; February 23, 1884 – November 19, 1967) was a Polish biochemist generally credited with being among the first to formulate the concept of vitamins after publishing a landmark medical writing in 1912. He highlighted these "vital amines" (or "vitamines") as critical in fighting significant diseases such as pellagra and rickets, and his analysis influenced a major shift in scientific thinking. His scientific work involved research in Poland, France and the United Kingdom. In 1920, he became a citizen of the United States where he continued his work. Early life and education He was born in Warsaw (the capital of Poland), being the son of a medical specialist in dermatology. In 1904, at the age of twenty, he earned a doctorate in chemistry at the University of Bern. In his early career, he worked as a biochemist at the Pasteur Institute, the Wiesbaden Municipal Hospital, the University of Berlin, and the Lister Institute. Funk emigrated to New York State in 1915, ...
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